Substitution and intramolecular rearrangement of trans-[ReO(X)(acac 2en/pn)]0/+ (X = OH2 or Cl-) to yield asymmetric cis-[ReO(Y)(acac2en/pn)] complexes with cyanide and thiocyanate

Jenny L. Green; Paul D. Benny; Hendrik P. Engelbrecht; Charles L. Barnes; Silvia S. Jurisson

doi:10.1081/SIM-200047547

Substitution and intramolecular rearrangement of trans-[ReO(X)(acac ₂en/pn)]^0/+ (X = OH₂ or Cl^-) to yield asymmetric cis-[ReO(Y)(acac₂en/pn)] complexes with cyanide and thiocyanate

Jenny L. Green, Paul D. Benny, Hendrik P. Engelbrecht, Charles L. Barnes, Silvia S. Jurisson

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Asymmetric Re(V) oxo complexes of the type cis-[ReO(Y) (acac ₂en/pn)] (Y = CN^-, NCS^-) were generated from the symmetric precursors trans-[ReO(X)(acac₂en/pn)]^0/+ (X = H₂O, Cl^-) by reaction with cyanide and thiocyanate. The products were characterized using standard spectroscopic methods, elemental analyses and single crystal X-ray diffraction. The crystallographic data for the structures reported are as follows: cis-[ReO(NCS)(acac₂pn)] (H ₂₀C₁₄N₃O₃SRe), 1, monoclinic (P2₁/n), a = 8.0047(6) Å, b = 13.6118 (10) Å, c = 30.597(2) Å, β = 96.571(1)°, V = 3311.9(4) Å³, Z = 8; cis-[ReO(CN)(acac₂pn)] (H₂₀C₁₄N ₃O₃Re), 2, monoclinic (P2₁/n), a = 9.5139(12) Å, b = 14.0625(18) Å, c = 12.2343(3) Å, = 107.286 (2)°, V = 1562.9(3) Å³, Z = 4; cis-[ReO(NCS)(acac₂en)] (H₁₈C₁₃N₃ O₃SRe), 3, monoclinic (P2₁/c), a = 17.1965(19) Å, b = 12.7416(14) Å, c = 15.7270(17) Å, = 110.589(2)°, V = 3225.9(6) Å³, Z = 8.

Original language	English
Pages (from-to)	53-59
Number of pages	7
Journal	Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry
Volume	35
Issue number	1
DOIs	https://doi.org/10.1081/SIM-200047547
State	Published - 2005
Externally published	Yes

Funding

The authors would like to gratefully acknowledge financial support from DOE grants DE-FG02-93ER61661 (JLG) and DE-FG2-01ER63192 (HPE) from the Radiochemistry Education Award Program administered by the South Carolina Universities Research and Education Foundation (under U.S. Department of Energy Cooperative Agreement #DE-FC09SR18262), Mallinckrodt Medical, Inc. (St. Louis, MO) and the National Science Foundation NSF CHE 9221835 (250 MHz NMR).

Funders	Funder number
JLG	DE-FG2-01ER63192
National Science Foundation	CHE 9221835
U.S. Department of Energy	DE-FG02-93ER61661, -FC09SR18262
South Carolina Universities Research and Education Foundation

Keywords

Re(V)-cyanide complex
Re(V)-thiocyanate complexes
Rhenium(V)
Schiffbase complexes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1081/SIM-200047547

Cite this

Green, J. L., Benny, P. D., Engelbrecht, H. P., Barnes, C. L., & Jurisson, S. S. (2005). Substitution and intramolecular rearrangement of trans-[ReO(X)(acac ₂en/pn)]^0/+ (X = OH₂ or Cl^-) to yield asymmetric cis-[ReO(Y)(acac₂en/pn)] complexes with cyanide and thiocyanate. Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, 35(1), 53-59. https://doi.org/10.1081/SIM-200047547

@article{a0d0ed4ea88d45ffbf4eff9553afcc01,

title = "Substitution and intramolecular rearrangement of trans-[ReO(X)(acac 2en/pn)]0/+ (X = OH2 or Cl-) to yield asymmetric cis-[ReO(Y)(acac2en/pn)] complexes with cyanide and thiocyanate",

abstract = "Asymmetric Re(V) oxo complexes of the type cis-[ReO(Y) (acac 2en/pn)] (Y = CN-, NCS-) were generated from the symmetric precursors trans-[ReO(X)(acac2en/pn)]0/+ (X = H2O, Cl-) by reaction with cyanide and thiocyanate. The products were characterized using standard spectroscopic methods, elemental analyses and single crystal X-ray diffraction. The crystallographic data for the structures reported are as follows: cis-[ReO(NCS)(acac2pn)] (H 20C14N3O3SRe), 1, monoclinic (P21/n), a = 8.0047(6) {\AA}, b = 13.6118 (10) {\AA}, c = 30.597(2) {\AA}, β = 96.571(1)°, V = 3311.9(4) {\AA}3, Z = 8; cis-[ReO(CN)(acac2pn)] (H20C14N 3O3Re), 2, monoclinic (P21/n), a = 9.5139(12) {\AA}, b = 14.0625(18) {\AA}, c = 12.2343(3) {\AA}, = 107.286 (2)°, V = 1562.9(3) {\AA}3, Z = 4; cis-[ReO(NCS)(acac2en)] (H18C13N3 O3SRe), 3, monoclinic (P21/c), a = 17.1965(19) {\AA}, b = 12.7416(14) {\AA}, c = 15.7270(17) {\AA}, = 110.589(2)°, V = 3225.9(6) {\AA}3, Z = 8.",

keywords = "Re(V)-cyanide complex, Re(V)-thiocyanate complexes, Rhenium(V), Schiffbase complexes",

author = "Green, {Jenny L.} and Benny, {Paul D.} and Engelbrecht, {Hendrik P.} and Barnes, {Charles L.} and Jurisson, {Silvia S.}",

year = "2005",

doi = "10.1081/SIM-200047547",

language = "English",

volume = "35",

pages = "53--59",

journal = "Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry",

issn = "1553-3174",

number = "1",

}

Green, JL, Benny, PD, Engelbrecht, HP, Barnes, CL & Jurisson, SS 2005, 'Substitution and intramolecular rearrangement of trans-[ReO(X)(acac ₂en/pn)]^0/+ (X = OH₂ or Cl^-) to yield asymmetric cis-[ReO(Y)(acac₂en/pn)] complexes with cyanide and thiocyanate', Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, vol. 35, no. 1, pp. 53-59. https://doi.org/10.1081/SIM-200047547

Substitution and intramolecular rearrangement of trans-[ReO(X)(acac ₂en/pn)]^0/+ (X = OH₂ or Cl^-) to yield asymmetric cis-[ReO(Y)(acac₂en/pn)] complexes with cyanide and thiocyanate. / Green, Jenny L.; Benny, Paul D.; Engelbrecht, Hendrik P. et al.
In: Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, Vol. 35, No. 1, 2005, p. 53-59.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Substitution and intramolecular rearrangement of trans-[ReO(X)(acac 2en/pn)]0/+ (X = OH2 or Cl-) to yield asymmetric cis-[ReO(Y)(acac2en/pn)] complexes with cyanide and thiocyanate

AU - Green, Jenny L.

AU - Benny, Paul D.

AU - Engelbrecht, Hendrik P.

AU - Barnes, Charles L.

AU - Jurisson, Silvia S.

PY - 2005

Y1 - 2005

N2 - Asymmetric Re(V) oxo complexes of the type cis-[ReO(Y) (acac 2en/pn)] (Y = CN-, NCS-) were generated from the symmetric precursors trans-[ReO(X)(acac2en/pn)]0/+ (X = H2O, Cl-) by reaction with cyanide and thiocyanate. The products were characterized using standard spectroscopic methods, elemental analyses and single crystal X-ray diffraction. The crystallographic data for the structures reported are as follows: cis-[ReO(NCS)(acac2pn)] (H 20C14N3O3SRe), 1, monoclinic (P21/n), a = 8.0047(6) Å, b = 13.6118 (10) Å, c = 30.597(2) Å, β = 96.571(1)°, V = 3311.9(4) Å3, Z = 8; cis-[ReO(CN)(acac2pn)] (H20C14N 3O3Re), 2, monoclinic (P21/n), a = 9.5139(12) Å, b = 14.0625(18) Å, c = 12.2343(3) Å, = 107.286 (2)°, V = 1562.9(3) Å3, Z = 4; cis-[ReO(NCS)(acac2en)] (H18C13N3 O3SRe), 3, monoclinic (P21/c), a = 17.1965(19) Å, b = 12.7416(14) Å, c = 15.7270(17) Å, = 110.589(2)°, V = 3225.9(6) Å3, Z = 8.

AB - Asymmetric Re(V) oxo complexes of the type cis-[ReO(Y) (acac 2en/pn)] (Y = CN-, NCS-) were generated from the symmetric precursors trans-[ReO(X)(acac2en/pn)]0/+ (X = H2O, Cl-) by reaction with cyanide and thiocyanate. The products were characterized using standard spectroscopic methods, elemental analyses and single crystal X-ray diffraction. The crystallographic data for the structures reported are as follows: cis-[ReO(NCS)(acac2pn)] (H 20C14N3O3SRe), 1, monoclinic (P21/n), a = 8.0047(6) Å, b = 13.6118 (10) Å, c = 30.597(2) Å, β = 96.571(1)°, V = 3311.9(4) Å3, Z = 8; cis-[ReO(CN)(acac2pn)] (H20C14N 3O3Re), 2, monoclinic (P21/n), a = 9.5139(12) Å, b = 14.0625(18) Å, c = 12.2343(3) Å, = 107.286 (2)°, V = 1562.9(3) Å3, Z = 4; cis-[ReO(NCS)(acac2en)] (H18C13N3 O3SRe), 3, monoclinic (P21/c), a = 17.1965(19) Å, b = 12.7416(14) Å, c = 15.7270(17) Å, = 110.589(2)°, V = 3225.9(6) Å3, Z = 8.

KW - Re(V)-cyanide complex

KW - Re(V)-thiocyanate complexes

KW - Rhenium(V)

KW - Schiffbase complexes

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U2 - 10.1081/SIM-200047547

DO - 10.1081/SIM-200047547

M3 - Article

AN - SCOPUS:18344389593

SN - 1553-3174

VL - 35

SP - 53

EP - 59

JO - Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry

JF - Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry

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