Studies and comparison of the liquid adsorption and surface properties of α-, β- and γ-cyclodextrins by FTIR and capillary rise method

Lv Fei Chen; Qing Shen; Ji Ping Shen; Dong Ting Shi; Ting Chen; Hao Ran Yu

doi:10.1016/j.colsurfa.2012.07.003

Studies and comparison of the liquid adsorption and surface properties of α-, β- and γ-cyclodextrins by FTIR and capillary rise method

Lv Fei Chen
, Qing Shen
, Ji Ping Shen
, Dong Ting Shi
, Ting Chen
, Hao Ran Yu

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

The liquid adsorption behavior and surface properties of α-, β-, and γ-cyclodextrin, CD, were studied and compared by FTIR and capillary rise method. These three CDs all showed an intense peak at 1155cm^-1 due to the C-O structure stretching and the peak height was found to reduce with the sugar ring molecules of CD increase. All these three CDs adsorbed the non-polar liquids greatly as compared with the polar liquid due to their total surface free energies dominated by the Lifshitz-van der Waals interactions component. The increase of the sugar ring molecules has been found to increase the Lewis acid-base property of CDs.

Original language	English
Pages (from-to)	69-73
Number of pages	5
Journal	Colloids and Surfaces A: Physicochemical and Engineering Aspects
Volume	411
DOIs	https://doi.org/10.1016/j.colsurfa.2012.07.003
State	Published - Oct 5 2012
Externally published	Yes

Keywords

Cyclodextrin
Liquid adsorption
Surface properties
α-, β-, γ-Structure

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10.1016/j.colsurfa.2012.07.003

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title = "Studies and comparison of the liquid adsorption and surface properties of α-, β- and γ-cyclodextrins by FTIR and capillary rise method",

abstract = "The liquid adsorption behavior and surface properties of α-, β-, and γ-cyclodextrin, CD, were studied and compared by FTIR and capillary rise method. These three CDs all showed an intense peak at 1155cm-1 due to the C-O structure stretching and the peak height was found to reduce with the sugar ring molecules of CD increase. All these three CDs adsorbed the non-polar liquids greatly as compared with the polar liquid due to their total surface free energies dominated by the Lifshitz-van der Waals interactions component. The increase of the sugar ring molecules has been found to increase the Lewis acid-base property of CDs.",

keywords = "Cyclodextrin, Liquid adsorption, Surface properties, α-, β-, γ-Structure",

author = "Chen, \{Lv Fei\} and Qing Shen and Shen, \{Ji Ping\} and Shi, \{Dong Ting\} and Ting Chen and Yu, \{Hao Ran\}",

year = "2012",

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doi = "10.1016/j.colsurfa.2012.07.003",

language = "English",

volume = "411",

pages = "69--73",

journal = "Colloids and Surfaces A: Physicochemical and Engineering Aspects",

issn = "0927-7757",

publisher = "Elsevier",

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TY - JOUR

T1 - Studies and comparison of the liquid adsorption and surface properties of α-, β- and γ-cyclodextrins by FTIR and capillary rise method

AU - Chen, Lv Fei

AU - Shen, Qing

AU - Shen, Ji Ping

AU - Shi, Dong Ting

AU - Chen, Ting

AU - Yu, Hao Ran

PY - 2012/10/5

Y1 - 2012/10/5

N2 - The liquid adsorption behavior and surface properties of α-, β-, and γ-cyclodextrin, CD, were studied and compared by FTIR and capillary rise method. These three CDs all showed an intense peak at 1155cm-1 due to the C-O structure stretching and the peak height was found to reduce with the sugar ring molecules of CD increase. All these three CDs adsorbed the non-polar liquids greatly as compared with the polar liquid due to their total surface free energies dominated by the Lifshitz-van der Waals interactions component. The increase of the sugar ring molecules has been found to increase the Lewis acid-base property of CDs.

AB - The liquid adsorption behavior and surface properties of α-, β-, and γ-cyclodextrin, CD, were studied and compared by FTIR and capillary rise method. These three CDs all showed an intense peak at 1155cm-1 due to the C-O structure stretching and the peak height was found to reduce with the sugar ring molecules of CD increase. All these three CDs adsorbed the non-polar liquids greatly as compared with the polar liquid due to their total surface free energies dominated by the Lifshitz-van der Waals interactions component. The increase of the sugar ring molecules has been found to increase the Lewis acid-base property of CDs.

KW - Cyclodextrin

KW - Liquid adsorption

KW - Surface properties

KW - α-, β-, γ-Structure

UR - https://www.scopus.com/pages/publications/84865106560

U2 - 10.1016/j.colsurfa.2012.07.003

DO - 10.1016/j.colsurfa.2012.07.003

M3 - Article

AN - SCOPUS:84865106560

SN - 0927-7757

VL - 411

SP - 69

EP - 73

JO - Colloids and Surfaces A: Physicochemical and Engineering Aspects

JF - Colloids and Surfaces A: Physicochemical and Engineering Aspects

ER -

Studies and comparison of the liquid adsorption and surface properties of α-, β- and γ-cyclodextrins by FTIR and capillary rise method

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Keywords

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