Structure, thermal properties and ionic conductivity of polymeric quaternary ammonium salts (polyionenes) containing ethylene oxide and aliphatic chain fragments

Michail V. Burmistr, Kostyantyn M. Sukhyy, Valery V. Shilov, Policarpos Pissis, George Polizos, Anna Spanoudaki, Yuri P. Gomza

Research output: Contribution to journalConference articlepeer-review

14 Scopus citations

Abstract

Wide-angle X-ray scattering, small-angle X-ray scattering, dielectric spectroscopy and differential scanning calorimetry were employed to study the structure and relaxation properties of polyionenes based on ethylene oxide units of different length. It was found that the heterogeneity of the supramolecular structure is increasing with the length of the ethylene oxide fragments. Polyionenes with short ethylene oxide segments have an amorphous structure. The temperature dependence of the dc-conductivity of the samples with short chain ethylene oxide interionic fragments followed the Arrhenius law, indicating a thermally activated conductivity, which is not typical for polymeric electrolytes. On the other hand, the conductivity of samples with longer ethylene oxide segments (more than nine ethylene oxide units) has a Vogel-Tammann-Fulcher type temperature dependence. The samples showed a high conductivity even at temperatures lower than the glass transition temperature, Tg, due to their structure, which resembles the structure of an inorganic glass with ionic sites dissolved in an ordered matrix.

Original languageEnglish
Pages (from-to)1787-1792
Number of pages6
JournalSolid State Ionics
Volume176
Issue number19-22
DOIs
StatePublished - Jun 2005
Externally publishedYes
EventProceedings of the 7th Internatioanl Symposium on Systems with Fast Ionic Transport -
Duration: May 5 2004May 9 2004

Funding

This work was carried out in the framework of the NATO Science Fellowships by the Greek Ministry of Foreign Affairs and supported through the Ukrainian Fundamental Research State Fund, Project 03.07/164.

Keywords

  • Decoupling index
  • Glass transition
  • Ionic conductivity
  • Polyelectrolytes
  • Polyionenes

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