Structure and properties of the Sr2In1-xSnxSbO6 double perovskite

Lun Jin; Danrui Ni; Xin Gui; Tai Kong; Duncan H. Moseley; Raphael P. Hermann; Robert J. Cava

doi:10.1016/j.jssc.2022.123355

Structure and properties of the Sr₂In_1-xSn_xSbO₆ double perovskite

Lun Jin, Danrui Ni, Xin Gui, Tai Kong, Duncan H. Moseley, Raphael P. Hermann, Robert J. Cava

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

A series of n-type oxide double perovskite semiconductors, Sr₂In_1-xSn_xSbO₆ (0 ≤ x ≤ 0.3) has been synthesized; Sn⁴⁺ partially substitutes for In³⁺. ¹²¹Sb and ¹¹⁹Sn Mössbauer spectroscopy are employed to investigate the B-site cation ordering because this issue cannot be resolved by conventional diffraction techniques alone. Rigid ordering between In³⁺/Sn⁴⁺ and Sb⁵⁺ sites is revealed by the spectroscopic method, and hence in combination with the structural parameters extracted from the XRD structural refinements, the crystallographic structure of this series of compounds is depicted. The temperature dependent magnetic susceptibilities, band gaps, and carrier type are characterized, and the calculated band structure is presented.

Original language	English
Article number	123355
Journal	Journal of Solid State Chemistry
Volume	314
DOIs	https://doi.org/10.1016/j.jssc.2022.123355
State	Published - Oct 2022

Funding

This research was primarily done at Princeton University , supported by the US Department of Energy , Division of Basic Energy Sciences , grant number DE-FG02-98ER45706 . The Mössbauer spectral work by DHM and RPH at Oak Ridge National Laboratory was supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Materials Sciences and Engineering Division.

Funders	Funder number
Division of Basic Energy Sciences	DE-FG02-98ER45706
U.S. Department of Energy
Office of Science
Basic Energy Sciences
Division of Materials Sciences and Engineering

Keywords

Band gaps
Band structures
Cation-ordered double perovskites
Mössbauer spectroscopy
X-ray powder diffraction
n-type semiconductors

Access to Document

10.1016/j.jssc.2022.123355

Cite this

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title = "Structure and properties of the Sr2In1-xSnxSbO6 double perovskite",

abstract = "A series of n-type oxide double perovskite semiconductors, Sr2In1-xSnxSbO6 (0 ≤ x ≤ 0.3) has been synthesized; Sn4+ partially substitutes for In3+. 121Sb and 119Sn M{\"o}ssbauer spectroscopy are employed to investigate the B-site cation ordering because this issue cannot be resolved by conventional diffraction techniques alone. Rigid ordering between In3+/Sn4+ and Sb5+ sites is revealed by the spectroscopic method, and hence in combination with the structural parameters extracted from the XRD structural refinements, the crystallographic structure of this series of compounds is depicted. The temperature dependent magnetic susceptibilities, band gaps, and carrier type are characterized, and the calculated band structure is presented.",

keywords = "Band gaps, Band structures, Cation-ordered double perovskites, M{\"o}ssbauer spectroscopy, X-ray powder diffraction, n-type semiconductors",

author = "Lun Jin and Danrui Ni and Xin Gui and Tai Kong and Moseley, {Duncan H.} and Hermann, {Raphael P.} and Cava, {Robert J.}",

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doi = "10.1016/j.jssc.2022.123355",

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T1 - Structure and properties of the Sr2In1-xSnxSbO6 double perovskite

AU - Jin, Lun

AU - Ni, Danrui

AU - Gui, Xin

AU - Kong, Tai

AU - Moseley, Duncan H.

AU - Hermann, Raphael P.

AU - Cava, Robert J.

PY - 2022/10

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AB - A series of n-type oxide double perovskite semiconductors, Sr2In1-xSnxSbO6 (0 ≤ x ≤ 0.3) has been synthesized; Sn4+ partially substitutes for In3+. 121Sb and 119Sn Mössbauer spectroscopy are employed to investigate the B-site cation ordering because this issue cannot be resolved by conventional diffraction techniques alone. Rigid ordering between In3+/Sn4+ and Sb5+ sites is revealed by the spectroscopic method, and hence in combination with the structural parameters extracted from the XRD structural refinements, the crystallographic structure of this series of compounds is depicted. The temperature dependent magnetic susceptibilities, band gaps, and carrier type are characterized, and the calculated band structure is presented.

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KW - Mössbauer spectroscopy

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