Structure and morphology of polar and semi-polar pyramidal surfaces coating wurtzite ZnO micro-wires

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    Abstract

    Wurtzite ZnO nano-pyramids grown by evaporation-deposition methods have been characterized using advanced electron microscopy. The basal and pyramidal planes of the nano-pyramids were identified as (0001) polar and 2021 semi-polar surfaces, respectively. The 2021 semi-polar surfaces were further faceted into 1011 semi-polar and 1010 non-polar surfaces. Surface area calculations revealed that approximately 65 % of the total surfaces of the as-grown nanostructures consisted of polar or semi-polar surfaces.

    Original languageEnglish
    Pages (from-to)3857-3862
    Number of pages6
    JournalJournal of Materials Science
    Volume48
    Issue number10
    DOIs
    StatePublished - May 2013

    Funding

    Acknowledgements Part of the synthesis work was conducted at and supported by the University of Missouri-St. Louis. The aberration-corrected electron microscopy work was performed at the Oak Ridge National Laboratory High Temperature Materials Laboratory, sponsored by the U. S. Department of Energy, Office of Energy Efficiency and Renewable Energy, Vehicle Technologies Program. The authors also gratefully acknowledge the use of facilities in the John M. Cowley Center for High-Resolution Electron Microscopy at Arizona State University.

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