Structure and magnetic properties of a new single-molecule magnet [Mn 11Fe1O12 (CH3COO) 16(H2O)4]·2CH 3COOH·4H2O

Hui Bo Cao; Lun Hua He; Fang Wei Wang

doi:10.1088/1009-1963/14/9/037

Structure and magnetic properties of a new single-molecule magnet [Mn ₁₁Fe₁O₁₂ (CH₃COO) ₁₆(H₂O)₄]·2CH ₃COOH·4H₂O

Hui Bo Cao, Lun Hua He, Fang Wei Wang

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

A new single-molecule magnet [Mn₁₁Fe₁O ₁₂(CH₃COO)₁₆(H₂O) ₄].2CH₃COOH.4H₂O (Mn₁₁Fe ₁) has been synthesized. The structure has been studied by the single crystal x-ray diffraction. The difference of Jahn-Teller distortion between Fe³⁺ and Mn³⁺ ion reveals that Fe³⁺ ion substitutes for Mn³⁺ ion on the Mn(3) sites in the Mn ₁₂ skeleton. The temperature dependence of the magnetization gives a blocking temperature T_B≤1.9K for Mn₁₁Fe₁. Based on the magnetization process analysis of the crystal at T≤2K, we suggest that Mn₁₁Fe₁ has the ground state with a total spin S≤ 11/2.

Original language	English
Pages (from-to)	1892-1895
Number of pages	4
Journal	Chinese Physics
Volume	14
Issue number	9
DOIs	https://doi.org/10.1088/1009-1963/14/9/037
State	Published - Sep 1 2005
Externally published	Yes

Keywords

Blocking temperature
Jahn-Teller distortion
Quantum tunnelling

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10.1088/1009-1963/14/9/037

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title = "Structure and magnetic properties of a new single-molecule magnet [Mn 11Fe1O12 (CH3COO) 16(H2O)4]·2CH 3COOH·4H2O",

abstract = "A new single-molecule magnet [Mn11Fe1O 12(CH3COO)16(H2O) 4].2CH3COOH.4H2O (Mn11Fe 1) has been synthesized. The structure has been studied by the single crystal x-ray diffraction. The difference of Jahn-Teller distortion between Fe3+ and Mn3+ ion reveals that Fe3+ ion substitutes for Mn3+ ion on the Mn(3) sites in the Mn 12 skeleton. The temperature dependence of the magnetization gives a blocking temperature TB≤1.9K for Mn11Fe1. Based on the magnetization process analysis of the crystal at T≤2K, we suggest that Mn11Fe1 has the ground state with a total spin S≤ 11/2.",

keywords = "Blocking temperature, Jahn-Teller distortion, Quantum tunnelling",

author = "Cao, {Hui Bo} and He, {Lun Hua} and Wang, {Fang Wei}",

year = "2005",

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doi = "10.1088/1009-1963/14/9/037",

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T1 - Structure and magnetic properties of a new single-molecule magnet [Mn 11Fe1O12 (CH3COO) 16(H2O)4]·2CH 3COOH·4H2O

AU - Cao, Hui Bo

AU - He, Lun Hua

AU - Wang, Fang Wei

PY - 2005/9/1

Y1 - 2005/9/1

N2 - A new single-molecule magnet [Mn11Fe1O 12(CH3COO)16(H2O) 4].2CH3COOH.4H2O (Mn11Fe 1) has been synthesized. The structure has been studied by the single crystal x-ray diffraction. The difference of Jahn-Teller distortion between Fe3+ and Mn3+ ion reveals that Fe3+ ion substitutes for Mn3+ ion on the Mn(3) sites in the Mn 12 skeleton. The temperature dependence of the magnetization gives a blocking temperature TB≤1.9K for Mn11Fe1. Based on the magnetization process analysis of the crystal at T≤2K, we suggest that Mn11Fe1 has the ground state with a total spin S≤ 11/2.

AB - A new single-molecule magnet [Mn11Fe1O 12(CH3COO)16(H2O) 4].2CH3COOH.4H2O (Mn11Fe 1) has been synthesized. The structure has been studied by the single crystal x-ray diffraction. The difference of Jahn-Teller distortion between Fe3+ and Mn3+ ion reveals that Fe3+ ion substitutes for Mn3+ ion on the Mn(3) sites in the Mn 12 skeleton. The temperature dependence of the magnetization gives a blocking temperature TB≤1.9K for Mn11Fe1. Based on the magnetization process analysis of the crystal at T≤2K, we suggest that Mn11Fe1 has the ground state with a total spin S≤ 11/2.

KW - Blocking temperature

KW - Jahn-Teller distortion

KW - Quantum tunnelling

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U2 - 10.1088/1009-1963/14/9/037

DO - 10.1088/1009-1963/14/9/037

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SN - 1009-1963

VL - 14

SP - 1892

EP - 1895

JO - Chinese Physics

JF - Chinese Physics

IS - 9

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Structure and magnetic properties of a new single-molecule magnet [Mn ₁₁Fe₁O₁₂ (CH₃COO) ₁₆(H₂O)₄]·2CH ₃COOH·4H₂O

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Keywords

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