Structure and luminescence of a 2-dimensional 2,3-pyridinedicarboxylate coordination polymer constructed from lanthanide(III) dimers

Amanda L. Ramirez; Karah E. Knope; Tanya T. Kelley; Natalie E. Greig; Jeffrey D. Einkauf; Daniel T. De Lill

doi:10.1016/j.ica.2012.05.039

Structure and luminescence of a 2-dimensional 2,3-pyridinedicarboxylate coordination polymer constructed from lanthanide(III) dimers

Amanda L. Ramirez, Karah E. Knope, Tanya T. Kelley, Natalie E. Greig, Jeffrey D. Einkauf, Daniel T. De Lill

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

A new two-dimensional lanthanide coordination polymer, [Ln(C ₇H₃NO₄)(C₇H₄NO ₄)(H₂O)]_n (Ln = trivalent Pr, Nd, Sm, Eu, and Tb) has been hydrothermally synthesized from reaction with 2,3- pyridinedicarboxylic acid. The compound crystallizes in the P2₁/c space group and is built from sheets composed of carboxylate-bridged Ln dimers stacked along the [1 0 0] direction and held together by hydrogen bonding between carboxylic acid groups. The organic component is successful at sensitizing lanthanide emission in the Sm, Eu, and Tb compounds with quantum yields experimentally determined of 0.60, 4.6, and 2.6%, respectively.

Original language	English
Pages (from-to)	46-51
Number of pages	6
Journal	Inorganica Chimica Acta
Volume	392
DOIs	https://doi.org/10.1016/j.ica.2012.05.039
State	Published - Sep 30 2012
Externally published	Yes

Funding

The authors would like to thank Florida Atlantic University for funding this project, particularly the Division of Undergraduate Research who awarded a research grant to T.T.K. for her work on the quantitative measurements of luminescence in lanthanide containing compounds. Work performed by K.E.K. was done at Argonne National Laboratory, operated by UChicagoArgonne LLC for the United States of America Department of Energy under contract number DE-AC-02-06CH11357 and was supported by a DOE Office of Basic Energy Sciences, Single-Investigator and Small-Group Research Project.

Funders	Funder number
America Department of Energy	DE-AC-02-06CH11357
DOE Office of Basic Energy Sciences
UChicagoArgonne LLC
Argonne National Laboratory
Florida Atlantic University

Keywords

Coordination polymer
Crystallography
Lanthanide
Luminescence
Quantum yield

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10.1016/j.ica.2012.05.039

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title = "Structure and luminescence of a 2-dimensional 2,3-pyridinedicarboxylate coordination polymer constructed from lanthanide(III) dimers",

abstract = "A new two-dimensional lanthanide coordination polymer, [Ln(C 7H3NO4)(C7H4NO 4)(H2O)]n (Ln = trivalent Pr, Nd, Sm, Eu, and Tb) has been hydrothermally synthesized from reaction with 2,3- pyridinedicarboxylic acid. The compound crystallizes in the P21/c space group and is built from sheets composed of carboxylate-bridged Ln dimers stacked along the [1 0 0] direction and held together by hydrogen bonding between carboxylic acid groups. The organic component is successful at sensitizing lanthanide emission in the Sm, Eu, and Tb compounds with quantum yields experimentally determined of 0.60, 4.6, and 2.6%, respectively.",

keywords = "Coordination polymer, Crystallography, Lanthanide, Luminescence, Quantum yield",

author = "Ramirez, {Amanda L.} and Knope, {Karah E.} and Kelley, {Tanya T.} and Greig, {Natalie E.} and Einkauf, {Jeffrey D.} and {De Lill}, {Daniel T.}",

year = "2012",

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doi = "10.1016/j.ica.2012.05.039",

language = "English",

volume = "392",

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journal = "Inorganica Chimica Acta",

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TY - JOUR

T1 - Structure and luminescence of a 2-dimensional 2,3-pyridinedicarboxylate coordination polymer constructed from lanthanide(III) dimers

AU - Ramirez, Amanda L.

AU - Knope, Karah E.

AU - Kelley, Tanya T.

AU - Greig, Natalie E.

AU - Einkauf, Jeffrey D.

AU - De Lill, Daniel T.

PY - 2012/9/30

Y1 - 2012/9/30

N2 - A new two-dimensional lanthanide coordination polymer, [Ln(C 7H3NO4)(C7H4NO 4)(H2O)]n (Ln = trivalent Pr, Nd, Sm, Eu, and Tb) has been hydrothermally synthesized from reaction with 2,3- pyridinedicarboxylic acid. The compound crystallizes in the P21/c space group and is built from sheets composed of carboxylate-bridged Ln dimers stacked along the [1 0 0] direction and held together by hydrogen bonding between carboxylic acid groups. The organic component is successful at sensitizing lanthanide emission in the Sm, Eu, and Tb compounds with quantum yields experimentally determined of 0.60, 4.6, and 2.6%, respectively.

AB - A new two-dimensional lanthanide coordination polymer, [Ln(C 7H3NO4)(C7H4NO 4)(H2O)]n (Ln = trivalent Pr, Nd, Sm, Eu, and Tb) has been hydrothermally synthesized from reaction with 2,3- pyridinedicarboxylic acid. The compound crystallizes in the P21/c space group and is built from sheets composed of carboxylate-bridged Ln dimers stacked along the [1 0 0] direction and held together by hydrogen bonding between carboxylic acid groups. The organic component is successful at sensitizing lanthanide emission in the Sm, Eu, and Tb compounds with quantum yields experimentally determined of 0.60, 4.6, and 2.6%, respectively.

KW - Coordination polymer

KW - Crystallography

KW - Lanthanide

KW - Luminescence

KW - Quantum yield

UR - http://www.scopus.com/inward/record.url?scp=84865286382&partnerID=8YFLogxK

U2 - 10.1016/j.ica.2012.05.039

DO - 10.1016/j.ica.2012.05.039

M3 - Article

AN - SCOPUS:84865286382

SN - 0020-1693

VL - 392

SP - 46

EP - 51

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

ER -

Structure and luminescence of a 2-dimensional 2,3-pyridinedicarboxylate coordination polymer constructed from lanthanide(III) dimers

Abstract

Funding

Keywords

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