Structure and conductivity of unsymmetrical π-donor ethylenedithiodithiadiselenafulvalene iodomercurate (EDT-DTDSF) 4Hg3I8

E. I. Zhilyaeva; A. Yu Kovalevskyi; S. A. Torunova; G. A. Mousdis; R. B. Lyubovskii; G. C. Papavassiliou; P. Coppens; R. N. Lyubovskaya

doi:10.1016/j.synthmet.2005.02.014

Structure and conductivity of unsymmetrical π-donor ethylenedithiodithiadiselenafulvalene iodomercurate (EDT-DTDSF) ₄Hg₃I₈

E. I. Zhilyaeva, A. Yu Kovalevskyi, S. A. Torunova, G. A. Mousdis, R. B. Lyubovskii, G. C. Papavassiliou, P. Coppens, R. N. Lyubovskaya

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

New charge transfer salt of Se-containing unsymmetrical donor ethylenedithiodithiadiselenafulvalene (EDT-DTDSF) with iodomercurate anion, β-(EDT-DTDSF)₄Hg₃I₈, has been synthesized. The structure of β-(EDT-DTDSF)₄Hg₃I₈ has been determined from single-crystal X-ray analysis, which reveals alternating conducting donor layers of the β-type packing with insulating layers formed by infinite chains of [Hg₂I₆]^2- anions and HgI₂ molecules. Transport properties have been investigated.

Original language	English
Pages (from-to)	245-250
Number of pages	6
Journal	Synthetic Metals
Volume	150
Issue number	3
DOIs	https://doi.org/10.1016/j.synthmet.2005.02.014
State	Published - May 10 2005
Externally published	Yes

Funding

The work was supported by the RFBR grant 04-03-32296.

Funders	Funder number
Russian Foundation for Basic Research	04-03-32296

Keywords

Electrical conductivity
Organic conductors based on radical cation salts
X-ray diffraction

Access to Document

10.1016/j.synthmet.2005.02.014

Cite this

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title = "Structure and conductivity of unsymmetrical π-donor ethylenedithiodithiadiselenafulvalene iodomercurate (EDT-DTDSF) 4Hg3I8",

abstract = "New charge transfer salt of Se-containing unsymmetrical donor ethylenedithiodithiadiselenafulvalene (EDT-DTDSF) with iodomercurate anion, β-(EDT-DTDSF)4Hg3I8, has been synthesized. The structure of β-(EDT-DTDSF)4Hg3I8 has been determined from single-crystal X-ray analysis, which reveals alternating conducting donor layers of the β-type packing with insulating layers formed by infinite chains of [Hg2I6]2- anions and HgI2 molecules. Transport properties have been investigated.",

keywords = "Electrical conductivity, Organic conductors based on radical cation salts, X-ray diffraction",

author = "Zhilyaeva, {E. I.} and Kovalevskyi, {A. Yu} and Torunova, {S. A.} and Mousdis, {G. A.} and Lyubovskii, {R. B.} and Papavassiliou, {G. C.} and P. Coppens and Lyubovskaya, {R. N.}",

year = "2005",

month = may,

day = "10",

doi = "10.1016/j.synthmet.2005.02.014",

language = "English",

volume = "150",

pages = "245--250",

journal = "Synthetic Metals",

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T1 - Structure and conductivity of unsymmetrical π-donor ethylenedithiodithiadiselenafulvalene iodomercurate (EDT-DTDSF) 4Hg3I8

AU - Zhilyaeva, E. I.

AU - Kovalevskyi, A. Yu

AU - Torunova, S. A.

AU - Mousdis, G. A.

AU - Lyubovskii, R. B.

AU - Papavassiliou, G. C.

AU - Coppens, P.

AU - Lyubovskaya, R. N.

PY - 2005/5/10

Y1 - 2005/5/10

N2 - New charge transfer salt of Se-containing unsymmetrical donor ethylenedithiodithiadiselenafulvalene (EDT-DTDSF) with iodomercurate anion, β-(EDT-DTDSF)4Hg3I8, has been synthesized. The structure of β-(EDT-DTDSF)4Hg3I8 has been determined from single-crystal X-ray analysis, which reveals alternating conducting donor layers of the β-type packing with insulating layers formed by infinite chains of [Hg2I6]2- anions and HgI2 molecules. Transport properties have been investigated.

AB - New charge transfer salt of Se-containing unsymmetrical donor ethylenedithiodithiadiselenafulvalene (EDT-DTDSF) with iodomercurate anion, β-(EDT-DTDSF)4Hg3I8, has been synthesized. The structure of β-(EDT-DTDSF)4Hg3I8 has been determined from single-crystal X-ray analysis, which reveals alternating conducting donor layers of the β-type packing with insulating layers formed by infinite chains of [Hg2I6]2- anions and HgI2 molecules. Transport properties have been investigated.

KW - Electrical conductivity

KW - Organic conductors based on radical cation salts

KW - X-ray diffraction

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