Structural transformation in a Li1.2Co0.1Mn 0.55Ni0.15O2 lithium-ion battery cathode during high-voltage hold

Debasish Mohanty; Sergiy Kalnaus; Roberta A. Meisner; Athena S. Safat; Jianlin Li; E. Andrew Payzant; Kevin Rhodes; David L. Wood; Claus Daniel

doi:10.1039/c3ra40510a

Structural transformation in a Li_1.2Co_0.1Mn _0.55Ni_0.15O₂ lithium-ion battery cathode during high-voltage hold

Debasish Mohanty
, Sergiy Kalnaus
, Roberta A. Meisner
, Athena S. Safat
, Jianlin Li
, E. Andrew Payzant
, Kevin Rhodes
, David L. Wood
, Claus Daniel

Research output: Contribution to journal › Article › peer-review

44 Scopus citations

Abstract

A decrease in the c-lattice parameter was observed in Li _1.2Co_0.1Mn_0.55Ni_0.15O₂ during constant voltage holding at 4.5 V by in situ X-ray diffraction. Comparison of magnetic susceptibility data before and after high-voltage hold reveals the change in average oxidation states of transition metal ions during high-voltage holding process. Transmission electron microscopy studies show the spinel reflections with fundamental trigonal spots from the particles after high-voltage hold indicating substantial structural modification. The structural transformation was believed to occur due to the oxygen release and/or the migration of transition metal cations to lithium layer during constant voltage holding.

Original language	English
Pages (from-to)	7479-7485
Number of pages	7
Journal	RSC Advances
Volume	3
Issue number	20
DOIs	https://doi.org/10.1039/c3ra40510a
State	Published - May 28 2013

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title = "Structural transformation in a Li1.2Co0.1Mn 0.55Ni0.15O2 lithium-ion battery cathode during high-voltage hold",

abstract = "A decrease in the c-lattice parameter was observed in Li 1.2Co0.1Mn0.55Ni0.15O2 during constant voltage holding at 4.5 V by in situ X-ray diffraction. Comparison of magnetic susceptibility data before and after high-voltage hold reveals the change in average oxidation states of transition metal ions during high-voltage holding process. Transmission electron microscopy studies show the spinel reflections with fundamental trigonal spots from the particles after high-voltage hold indicating substantial structural modification. The structural transformation was believed to occur due to the oxygen release and/or the migration of transition metal cations to lithium layer during constant voltage holding.",

author = "Debasish Mohanty and Sergiy Kalnaus and Meisner, \{Roberta A.\} and Safat, \{Athena S.\} and Jianlin Li and Payzant, \{E. Andrew\} and Kevin Rhodes and Wood, \{David L.\} and Claus Daniel",

year = "2013",

month = may,

day = "28",

doi = "10.1039/c3ra40510a",

language = "English",

volume = "3",

pages = "7479--7485",

journal = "RSC Advances",

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TY - JOUR

T1 - Structural transformation in a Li1.2Co0.1Mn 0.55Ni0.15O2 lithium-ion battery cathode during high-voltage hold

AU - Mohanty, Debasish

AU - Kalnaus, Sergiy

AU - Meisner, Roberta A.

AU - Safat, Athena S.

AU - Li, Jianlin

AU - Payzant, E. Andrew

AU - Rhodes, Kevin

AU - Wood, David L.

AU - Daniel, Claus

PY - 2013/5/28

Y1 - 2013/5/28

N2 - A decrease in the c-lattice parameter was observed in Li 1.2Co0.1Mn0.55Ni0.15O2 during constant voltage holding at 4.5 V by in situ X-ray diffraction. Comparison of magnetic susceptibility data before and after high-voltage hold reveals the change in average oxidation states of transition metal ions during high-voltage holding process. Transmission electron microscopy studies show the spinel reflections with fundamental trigonal spots from the particles after high-voltage hold indicating substantial structural modification. The structural transformation was believed to occur due to the oxygen release and/or the migration of transition metal cations to lithium layer during constant voltage holding.

AB - A decrease in the c-lattice parameter was observed in Li 1.2Co0.1Mn0.55Ni0.15O2 during constant voltage holding at 4.5 V by in situ X-ray diffraction. Comparison of magnetic susceptibility data before and after high-voltage hold reveals the change in average oxidation states of transition metal ions during high-voltage holding process. Transmission electron microscopy studies show the spinel reflections with fundamental trigonal spots from the particles after high-voltage hold indicating substantial structural modification. The structural transformation was believed to occur due to the oxygen release and/or the migration of transition metal cations to lithium layer during constant voltage holding.

UR - https://www.scopus.com/pages/publications/84877307850

U2 - 10.1039/c3ra40510a

DO - 10.1039/c3ra40510a

M3 - Article

AN - SCOPUS:84877307850

SN - 2046-2069

VL - 3

SP - 7479

EP - 7485

JO - RSC Advances

JF - RSC Advances

IS - 20

ER -

Structural transformation in a Li_1.2Co_0.1Mn _0.55Ni_0.15O₂ lithium-ion battery cathode during high-voltage hold

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