Structural Evidence of the Aromaticity of Borepins: A Comparison of 1‐Chloroborepin and Tricarbonyl(1‐chloroborepin)molybdenum

Arthur J. Ashe; Jeff W. Kampf; Wolfram Klein; Roger Rousseau

doi:10.1002/anie.199310651

Structural Evidence of the Aromaticity of Borepins: A Comparison of 1‐Chloroborepin and Tricarbonyl(1‐chloroborepin)molybdenum

Arthur J. Ashe, Jeff W. Kampf, Wolfram Klein, Roger Rousseau

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

A planar structure with C_2v symmetry is a description of 1‐chloroborepin 1, and is consistent with the presumption that 1 and probably also 1 H‐borepin are aromatic compounds. The Mo(CO)₃ complex was prepared from 1. Its structure was also determined, and it could be reduced to the stable complex 2. (Figure Presented.)

Original language	English
Pages (from-to)	1065-1066
Number of pages	2
Journal	Angewandte Chemie - International Edition
Volume	32
Issue number	7
DOIs	https://doi.org/10.1002/anie.199310651
State	Published - Jul 1993
Externally published	Yes

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title = "Structural Evidence of the Aromaticity of Borepins: A Comparison of 1‐Chloroborepin and Tricarbonyl(1‐chloroborepin)molybdenum",

abstract = "A planar structure with C2v symmetry is a description of 1‐chloroborepin 1, and is consistent with the presumption that 1 and probably also 1 H‐borepin are aromatic compounds. The Mo(CO)3 complex was prepared from 1. Its structure was also determined, and it could be reduced to the stable complex 2. (Figure Presented.)",

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year = "1993",

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T2 - A Comparison of 1‐Chloroborepin and Tricarbonyl(1‐chloroborepin)molybdenum

AU - Ashe, Arthur J.

AU - Kampf, Jeff W.

AU - Klein, Wolfram

AU - Rousseau, Roger

PY - 1993/7

Y1 - 1993/7

N2 - A planar structure with C2v symmetry is a description of 1‐chloroborepin 1, and is consistent with the presumption that 1 and probably also 1 H‐borepin are aromatic compounds. The Mo(CO)3 complex was prepared from 1. Its structure was also determined, and it could be reduced to the stable complex 2. (Figure Presented.)

AB - A planar structure with C2v symmetry is a description of 1‐chloroborepin 1, and is consistent with the presumption that 1 and probably also 1 H‐borepin are aromatic compounds. The Mo(CO)3 complex was prepared from 1. Its structure was also determined, and it could be reduced to the stable complex 2. (Figure Presented.)

UR - https://www.scopus.com/pages/publications/33748215301

U2 - 10.1002/anie.199310651

DO - 10.1002/anie.199310651

M3 - Article

AN - SCOPUS:33748215301

SN - 0570-0833

VL - 32

SP - 1065

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 7

ER -

Structural Evidence of the Aromaticity of Borepins: A Comparison of 1‐Chloroborepin and Tricarbonyl(1‐chloroborepin)molybdenum

Abstract

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