Structural aspects of lithium-manganese-oxide electrodes for rechargeable lithium batteries

MH Rossouw; A. de Kock; LA de Picciotto; MM Thackeray; WIF David; RM Ibberson

doi:10.1016/0025-5408(90)90043-2

Structural aspects of lithium-manganese-oxide electrodes for rechargeable lithium batteries

MH Rossouw, A. de Kock, LA de Picciotto, MM Thackeray, WIF David, RM Ibberson

Research output: Contribution to journal › Article › peer-review

160 Scopus citations

Abstract

The structural characteristics of "Li_xMnO_y" electrodes, prepared by reacting manganese oxides with lithium salts at 400°C-900°C, for ambient temperature, rechargeable lithium cells have been determined by powder X-ray and neutron diffraction studies. The identification of structure types and cyclic voltammetry data show that the rechargeability of the "Li_xMnO_y" electrodes in Li "Li_xMnO_y" cells can be attributed predominantly to a spinel component of the system Li_xMn_2-zO₄ (0≤x≤1.33 and 0≤z≤0.33) which includes the spinel phases LiMn₂O₄, Li₂Mn₄O₉ and Li₄Mn₅O₁₂.

Original language	English
Pages (from-to)	173-182
Number of pages	10
Journal	Materials Research Bulletin
Volume	25
Issue number	2
DOIs	https://doi.org/10.1016/0025-5408(90)90043-2
State	Published - Feb 1990
Externally published	Yes

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title = "Structural aspects of lithium-manganese-oxide electrodes for rechargeable lithium batteries",

abstract = "The structural characteristics of {"}LixMnOy{"} electrodes, prepared by reacting manganese oxides with lithium salts at 400°C-900°C, for ambient temperature, rechargeable lithium cells have been determined by powder X-ray and neutron diffraction studies. The identification of structure types and cyclic voltammetry data show that the rechargeability of the {"}LixMnOy{"} electrodes in Li {"}LixMnOy{"} cells can be attributed predominantly to a spinel component of the system LixMn2-zO4 (0≤x≤1.33 and 0≤z≤0.33) which includes the spinel phases LiMn2O4, Li2Mn4O9 and Li4Mn5O12.",

author = "MH Rossouw and {de Kock}, A. and {de Picciotto}, LA and MM Thackeray and WIF David and RM Ibberson",

year = "1990",

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T1 - Structural aspects of lithium-manganese-oxide electrodes for rechargeable lithium batteries

AU - Rossouw, MH

AU - de Kock, A.

AU - de Picciotto, LA

AU - Thackeray, MM

AU - David, WIF

AU - Ibberson, RM

PY - 1990/2

Y1 - 1990/2

N2 - The structural characteristics of "LixMnOy" electrodes, prepared by reacting manganese oxides with lithium salts at 400°C-900°C, for ambient temperature, rechargeable lithium cells have been determined by powder X-ray and neutron diffraction studies. The identification of structure types and cyclic voltammetry data show that the rechargeability of the "LixMnOy" electrodes in Li "LixMnOy" cells can be attributed predominantly to a spinel component of the system LixMn2-zO4 (0≤x≤1.33 and 0≤z≤0.33) which includes the spinel phases LiMn2O4, Li2Mn4O9 and Li4Mn5O12.

AB - The structural characteristics of "LixMnOy" electrodes, prepared by reacting manganese oxides with lithium salts at 400°C-900°C, for ambient temperature, rechargeable lithium cells have been determined by powder X-ray and neutron diffraction studies. The identification of structure types and cyclic voltammetry data show that the rechargeability of the "LixMnOy" electrodes in Li "LixMnOy" cells can be attributed predominantly to a spinel component of the system LixMn2-zO4 (0≤x≤1.33 and 0≤z≤0.33) which includes the spinel phases LiMn2O4, Li2Mn4O9 and Li4Mn5O12.

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U2 - 10.1016/0025-5408(90)90043-2

DO - 10.1016/0025-5408(90)90043-2

M3 - Article

AN - SCOPUS:0025030843

SN - 0025-5408

VL - 25

SP - 173

EP - 182

JO - Materials Research Bulletin

JF - Materials Research Bulletin

IS - 2

ER -

Structural aspects of lithium-manganese-oxide electrodes for rechargeable lithium batteries

Abstract

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