Structural and chemical stability of high performance Ce0.8Gd0.2O2-Δ – FeCo2O4 dual phase oxygen transport membranes

M. Ramasamy, E. S. Persoon, S. Baumann, M. Schroeder, F. Schulze-Küppers, D. Görtz, R. Bhave, M. Bram, W. A. Meulenberg

Research output: Contribution to journalArticlepeer-review

25 Scopus citations

Abstract

Ceramic oxide membranes are widely being researched for Carbon Capture and Storage/Utilization sector applications. Foreseen applications of these membranes are oxygen generation for oxyfuel combustion in e.g. power plants, glass-, cement- or steel production. Major drawback with Mixed Ionic and Electronic Conducting (MIEC) perovskite structure membranes is their limited long term stability at high temperatures in aggressive atmospheres. Dual phase composite membranes have been reported to excel overcoming this drawback. In addition to performance evaluation, Ce0.8Gd0.2O2-δ – FeCo2O4 (CGO-FCO) membranes were subjected to stability test in flue gas conditions closely mimicking industrial flue gas atmosphere. The dual phase composites are investigated for their phase stability at the operating temperature of 850 °C in a gradient of oxygen chemical potential. The composites were also exposed to a series of gas mixtures over a period of time at their operating temperature to test for the chemical stability. CGO-FCO membranes are identified to possess chemical stability in gas mixtures of CO2, SO2 along with oxygen over a period of 200 h at 850 °C under oxygen partial pressure gradient.

Original languageEnglish
Pages (from-to)278-286
Number of pages9
JournalJournal of Membrane Science
Volume544
DOIs
StatePublished - 2017

Funding

This work has been funded by the Federal Ministry of Education and Research , Germany (BMBF) (Grant: 03EK3032 ) and the European Commission via the FP7 project GREEN-CC (Grant agreement no. 608524 ). The authors acknowledge the support of Dr. D. Sebold for part of the SEM analyses, Dr. J. Sohn for Rietveld refinement of X-ray analysis data, Mr. S. Heinz for his technical assistance in sample preparation (Forschungszentrum Jülich GmbH) and Mr. L. E. Powell (ORNL) for helping with the short term stability test setup.

Fingerprint

Dive into the research topics of 'Structural and chemical stability of high performance Ce0.8Gd0.2O2-Δ – FeCo2O4 dual phase oxygen transport membranes'. Together they form a unique fingerprint.

Cite this