Abstract
We have used time-of-flight inelastic neutron scattering to measure the spin wave spectrum of the canonical half-doped manganite Pr0.5Ca0.5MnO3 in its magnetic and orbitally ordered phase. The data, which cover multiple Brillouin zones and the entire energy range of the excitations, are compared with several different models that are all consistent with CE-type magnetic order, but arise through different exchange coupling schemes. The Goodenough model, i.e., an ordered state comprising strong nearest-neighbor ferromagnetic interactions along zigzag chains with antiferromagnetic interchain coupling, provides the best description of the data, provided that further neighbor interactions along the chains are included. We are able to rule out a coupling scheme involving formation of strongly bound ferromagnetic dimers, i.e., Zener polarons, on the basis of gross features of the observed spin wave spectrum. A model with weaker dimerization reproduces the observed dispersion but can be ruled out on the basis of discrepancies between the calculated and observed structure factors at certain positions in reciprocal space. Adding further neighbor interactions results in almost no dimerization, i.e., recovery of the Goodenough model. These results are consistent with theoretical analysis of the degenerate double exchange model for half-doping, and provide a recipe for how to interpret future measurements away from half-doping, where degenerate double exchange models predict more complex ground states.
Original language | English |
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Article number | 014405 |
Journal | Physical Review B |
Volume | 94 |
Issue number | 1 |
DOIs | |
State | Published - Jul 6 2016 |
Funding
We are grateful to A. Daoud-Aladine, G. A. Sawatzky, J. P. Hill, and F. Krger for helpful discussions, and to A. J. Wenban for work on the dimer spin wave model. This work was supported by the Science and Technology Facilities Council of Great Britain. O.S. acknowledges support by the Polish National Science Center (NCN) under Project. No. 2012/04/A/ST3/00331 and EPSRC Grant EP/G0314060/1. Research at ORNL's Spallation Neutron Source was sponsored by the Scientific User Facilities Division, Office of Basic Energy Sciences, the US Department of Energy.
Funders | Funder number |
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Polish National Science Center | |
Science and Technology Facilities Council of Great Britain | |
Scientific User Facilities Division | |
U.S. Department of Energy | |
Basic Energy Sciences | |
Engineering and Physical Sciences Research Council | EP/G0314060/1 |
Narodowe Centrum Nauki | 2012/04/A/ST3/00331 |