Spectroscopic properties and reactivity of a mononuclear oxomanganese(IV) complex

Domenick F. Leto; Rena Ingram; Victor W. Day; Timothy A. Jackson

doi:10.1039/c3cc00244f

Spectroscopic properties and reactivity of a mononuclear oxomanganese(IV) complex

Domenick F. Leto, Rena Ingram, Victor W. Day, Timothy A. Jackson

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73 Scopus citations

Abstract

A non-porphyrinic, mononuclear oxomanganese(IV) complex was generated at room temperature and characterized by spectroscopic methods. The Mn^IV = O adduct is capable of activating C–H bonds by a H-atom transfer mechanism and is more reactive in this regard than most Mn^IV = O species.

Original language	English
Pages (from-to)	5378-5380
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	47
DOIs	https://doi.org/10.1039/c3cc00244f
State	Published - May 16 2013
Externally published	Yes

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title = "Spectroscopic properties and reactivity of a mononuclear oxomanganese(IV) complex",

abstract = "A non-porphyrinic, mononuclear oxomanganese(IV) complex was generated at room temperature and characterized by spectroscopic methods. The MnIV = O adduct is capable of activating C–H bonds by a H-atom transfer mechanism and is more reactive in this regard than most MnIV = O species.",

author = "Leto, \{Domenick F.\} and Rena Ingram and Day, \{Victor W.\} and Jackson, \{Timothy A.\}",

year = "2013",

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T1 - Spectroscopic properties and reactivity of a mononuclear oxomanganese(IV) complex

AU - Leto, Domenick F.

AU - Ingram, Rena

AU - Day, Victor W.

AU - Jackson, Timothy A.

PY - 2013/5/16

Y1 - 2013/5/16

N2 - A non-porphyrinic, mononuclear oxomanganese(IV) complex was generated at room temperature and characterized by spectroscopic methods. The MnIV = O adduct is capable of activating C–H bonds by a H-atom transfer mechanism and is more reactive in this regard than most MnIV = O species.

AB - A non-porphyrinic, mononuclear oxomanganese(IV) complex was generated at room temperature and characterized by spectroscopic methods. The MnIV = O adduct is capable of activating C–H bonds by a H-atom transfer mechanism and is more reactive in this regard than most MnIV = O species.

UR - https://www.scopus.com/pages/publications/84878071771

U2 - 10.1039/c3cc00244f

DO - 10.1039/c3cc00244f

M3 - Article

C2 - 23657204

AN - SCOPUS:84878071771

SN - 1359-7345

VL - 49

SP - 5378

EP - 5380

JO - Chemical Communications

JF - Chemical Communications

IS - 47

ER -

Spectroscopic properties and reactivity of a mononuclear oxomanganese(IV) complex

Abstract

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