Spectroscopic properties and reactivity of a mononuclear oxomanganese(IV) complex

Domenick F. Leto; Rena Ingram; Victor W. Day; Timothy A. Jackson

doi:10.1039/c3cc00244f

Spectroscopic properties and reactivity of a mononuclear oxomanganese(IV) complex

Domenick F. Leto, Rena Ingram, Victor W. Day, Timothy A. Jackson

University of Kansas

Research output: Contribution to journal › Article › peer-review

69 Scopus citations

Abstract

A non-porphyrinic, mononuclear oxomanganese(IV) complex was generated at room temperature and characterized by spectroscopic methods. The Mn^IV = O adduct is capable of activating C–H bonds by a H-atom transfer mechanism and is more reactive in this regard than most Mn^IV = O species.

Original language	English
Pages (from-to)	5378-5380
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	47
DOIs	https://doi.org/10.1039/c3cc00244f
State	Published - May 16 2013
Externally published	Yes

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title = "Spectroscopic properties and reactivity of a mononuclear oxomanganese(IV) complex",

abstract = "A non-porphyrinic, mononuclear oxomanganese(IV) complex was generated at room temperature and characterized by spectroscopic methods. The MnIV = O adduct is capable of activating C–H bonds by a H-atom transfer mechanism and is more reactive in this regard than most MnIV = O species.",

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AU - Leto, Domenick F.

AU - Ingram, Rena

AU - Day, Victor W.

AU - Jackson, Timothy A.

PY - 2013/5/16

Y1 - 2013/5/16

N2 - A non-porphyrinic, mononuclear oxomanganese(IV) complex was generated at room temperature and characterized by spectroscopic methods. The MnIV = O adduct is capable of activating C–H bonds by a H-atom transfer mechanism and is more reactive in this regard than most MnIV = O species.

AB - A non-porphyrinic, mononuclear oxomanganese(IV) complex was generated at room temperature and characterized by spectroscopic methods. The MnIV = O adduct is capable of activating C–H bonds by a H-atom transfer mechanism and is more reactive in this regard than most MnIV = O species.

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U2 - 10.1039/c3cc00244f

DO - 10.1039/c3cc00244f

M3 - Article

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AN - SCOPUS:84878071771

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VL - 49

SP - 5378

EP - 5380

JO - Chemical Communications

JF - Chemical Communications

IS - 47

ER -

Spectroscopic properties and reactivity of a mononuclear oxomanganese(IV) complex

Abstract

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