TY - JOUR
T1 - Spectral shape simplicity of viscous materials
AU - Gainaru, Catalin
N1 - Publisher Copyright:
© 2019 American Physical Society.
PY - 2019/8/12
Y1 - 2019/8/12
N2 - A broad survey of viscoelastic data demonstrates that van der Waals, hydrogen-bonded, and ionic liquids, as well as polymeric, inorganic, and metallic melts share a structural relaxation pattern virtually insensitive to their morphological details. This mechanical simplicity is connected with that characterizing the fast reorientation dynamics prevailing in liquids devoid of a distinguishable secondary susceptibility peak. By these means one is able to uncover a generic spectral pattern which rationalizes the recently reported "universality" of relaxation strength vs stretching of the dielectric response of viscous liquids, significantly broadening the framework in which their relaxation behavior is assessed.
AB - A broad survey of viscoelastic data demonstrates that van der Waals, hydrogen-bonded, and ionic liquids, as well as polymeric, inorganic, and metallic melts share a structural relaxation pattern virtually insensitive to their morphological details. This mechanical simplicity is connected with that characterizing the fast reorientation dynamics prevailing in liquids devoid of a distinguishable secondary susceptibility peak. By these means one is able to uncover a generic spectral pattern which rationalizes the recently reported "universality" of relaxation strength vs stretching of the dielectric response of viscous liquids, significantly broadening the framework in which their relaxation behavior is assessed.
UR - http://www.scopus.com/inward/record.url?scp=85070684942&partnerID=8YFLogxK
U2 - 10.1103/PhysRevE.100.020601
DO - 10.1103/PhysRevE.100.020601
M3 - Article
C2 - 31574661
AN - SCOPUS:85070684942
SN - 2470-0045
VL - 100
JO - Physical Review E - Statistical, Nonlinear, and Soft Matter Physics
JF - Physical Review E - Statistical, Nonlinear, and Soft Matter Physics
IS - 2
M1 - 020601
ER -