Sonochemical synthesis of C60H2

D. Mandrus; M. Kele; R. L. Hettich; G. Guiochon; B. C. Sales; L. A. Boatner

doi:10.1021/jp962056e

Sonochemical synthesis of C₆₀H₂

D. Mandrus
, M. Kele
, R. L. Hettich
, G. Guiochon
, B. C. Sales
, L. A. Boatner

Research output: Contribution to journal › Article › peer-review

41 Scopus citations

Abstract

C₆₀H₂ has been synthesized by ultrasonically irradiating solutions of C₆₀ in decahydronaphthalene. This synthesis can be understood as a secondary reaction arising from the production of atomic hydrogen during sonolysis of the solvent. Continued sonication results in the eventual disappearance of both C₆₀ and C₆₀H₂ from the solution as monitored by UV-vis spectrophotometry. This disappearance, along with the complete absence of more highly hydrogenated derivatives, suggests that the C₆₀ experiences a high-energy environment during ultrasonic irradiation.

Original language	English
Pages (from-to)	123-128
Number of pages	6
Journal	Journal of Physical Chemistry B
Volume	101
Issue number	2
DOIs	https://doi.org/10.1021/jp962056e
State	Published - Jan 9 1997

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abstract = "C60H2 has been synthesized by ultrasonically irradiating solutions of C60 in decahydronaphthalene. This synthesis can be understood as a secondary reaction arising from the production of atomic hydrogen during sonolysis of the solvent. Continued sonication results in the eventual disappearance of both C60 and C60H2 from the solution as monitored by UV-vis spectrophotometry. This disappearance, along with the complete absence of more highly hydrogenated derivatives, suggests that the C60 experiences a high-energy environment during ultrasonic irradiation.",

author = "D. Mandrus and M. Kele and Hettich, \{R. L.\} and G. Guiochon and Sales, \{B. C.\} and Boatner, \{L. A.\}",

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T1 - Sonochemical synthesis of C60H2

AU - Mandrus, D.

AU - Kele, M.

AU - Hettich, R. L.

AU - Guiochon, G.

AU - Sales, B. C.

AU - Boatner, L. A.

PY - 1997/1/9

Y1 - 1997/1/9

N2 - C60H2 has been synthesized by ultrasonically irradiating solutions of C60 in decahydronaphthalene. This synthesis can be understood as a secondary reaction arising from the production of atomic hydrogen during sonolysis of the solvent. Continued sonication results in the eventual disappearance of both C60 and C60H2 from the solution as monitored by UV-vis spectrophotometry. This disappearance, along with the complete absence of more highly hydrogenated derivatives, suggests that the C60 experiences a high-energy environment during ultrasonic irradiation.

AB - C60H2 has been synthesized by ultrasonically irradiating solutions of C60 in decahydronaphthalene. This synthesis can be understood as a secondary reaction arising from the production of atomic hydrogen during sonolysis of the solvent. Continued sonication results in the eventual disappearance of both C60 and C60H2 from the solution as monitored by UV-vis spectrophotometry. This disappearance, along with the complete absence of more highly hydrogenated derivatives, suggests that the C60 experiences a high-energy environment during ultrasonic irradiation.

UR - https://www.scopus.com/pages/publications/0031560509

U2 - 10.1021/jp962056e

DO - 10.1021/jp962056e

M3 - Article

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SN - 1520-6106

VL - 101

SP - 123

EP - 128

JO - Journal of Physical Chemistry B

JF - Journal of Physical Chemistry B

IS - 2

ER -

Sonochemical synthesis of C₆₀H₂

Abstract

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