Sonochemical synthesis of C60H2

D. Mandrus; M. Kele; R. L. Hettich; G. Guiochon; B. C. Sales; L. A. Boatner

doi:10.1021/jp962056e

Sonochemical synthesis of C₆₀H₂

D. Mandrus, M. Kele, R. L. Hettich, G. Guiochon, B. C. Sales, L. A. Boatner

Bioanalytical Mass Spectrometry

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38 Scopus citations

Abstract

C₆₀H₂ has been synthesized by ultrasonically irradiating solutions of C₆₀ in decahydronaphthalene. This synthesis can be understood as a secondary reaction arising from the production of atomic hydrogen during sonolysis of the solvent. Continued sonication results in the eventual disappearance of both C₆₀ and C₆₀H₂ from the solution as monitored by UV-vis spectrophotometry. This disappearance, along with the complete absence of more highly hydrogenated derivatives, suggests that the C₆₀ experiences a high-energy environment during ultrasonic irradiation.

Original language	English
Pages (from-to)	123-128
Number of pages	6
Journal	Journal of Physical Chemistry B
Volume	101
Issue number	2
DOIs	https://doi.org/10.1021/jp962056e
State	Published - Jan 9 1997

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abstract = "C60H2 has been synthesized by ultrasonically irradiating solutions of C60 in decahydronaphthalene. This synthesis can be understood as a secondary reaction arising from the production of atomic hydrogen during sonolysis of the solvent. Continued sonication results in the eventual disappearance of both C60 and C60H2 from the solution as monitored by UV-vis spectrophotometry. This disappearance, along with the complete absence of more highly hydrogenated derivatives, suggests that the C60 experiences a high-energy environment during ultrasonic irradiation.",

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AU - Mandrus, D.

AU - Kele, M.

AU - Hettich, R. L.

AU - Guiochon, G.

AU - Sales, B. C.

AU - Boatner, L. A.

PY - 1997/1/9

Y1 - 1997/1/9

N2 - C60H2 has been synthesized by ultrasonically irradiating solutions of C60 in decahydronaphthalene. This synthesis can be understood as a secondary reaction arising from the production of atomic hydrogen during sonolysis of the solvent. Continued sonication results in the eventual disappearance of both C60 and C60H2 from the solution as monitored by UV-vis spectrophotometry. This disappearance, along with the complete absence of more highly hydrogenated derivatives, suggests that the C60 experiences a high-energy environment during ultrasonic irradiation.

AB - C60H2 has been synthesized by ultrasonically irradiating solutions of C60 in decahydronaphthalene. This synthesis can be understood as a secondary reaction arising from the production of atomic hydrogen during sonolysis of the solvent. Continued sonication results in the eventual disappearance of both C60 and C60H2 from the solution as monitored by UV-vis spectrophotometry. This disappearance, along with the complete absence of more highly hydrogenated derivatives, suggests that the C60 experiences a high-energy environment during ultrasonic irradiation.

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JO - Journal of Physical Chemistry B

JF - Journal of Physical Chemistry B

IS - 2

ER -

Sonochemical synthesis of C₆₀H₂

Abstract

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