Solvent-free fabrication of ferromagnetic fe3o4 octahedra

Vilas G. Pol; Luke L. Daemen; Sven Vogel; George Chertkov

doi:10.1021/ie9011062

Solvent-free fabrication of ferromagnetic fe₃o₄ octahedra

Vilas G. Pol
, Luke L. Daemen
, Sven Vogel
, George Chertkov

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

The controlled thermolysis of a presynthesized single precursor, Fe ₃(CH₃COO)₆(OH)₂CH₃COO, in a closed reactor at 700 °C in an inert atmosphere produced ferromagnetic Fe₃O₄ octahedra without using solvent or catalyst. The octahedral shape with the 6-10 μm diameter of Fe₃O₄ is realized using field emission scanning electron microscope, and the composition, with an attached energy dispersive X-ray analyzer. The single-crystalline face-centered cubic structure of Fe₃O₄ octahedra is analyzed by X-ray diffraction measurements, further supported by Raman spectroscopy and transmission electron microscopy. The thermogravimetric analysis measured the amount of carbon present on the Fe₃O ₄ octahedra surfaces. The vibrating magnetometer corroborated ferromagnetic behavior of Fe₃O₄ octahedra with 150 Oe coercive force, 48 emu/g saturation magnetization, and 5 emu/g remnent magnetization.

Original language	English
Pages (from-to)	920-924
Number of pages	5
Journal	Industrial and Engineering Chemistry Research
Volume	49
Issue number	2
DOIs	https://doi.org/10.1021/ie9011062
State	Published - Jan 20 2010
Externally published	Yes

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title = "Solvent-free fabrication of ferromagnetic fe3o4 octahedra",

abstract = "The controlled thermolysis of a presynthesized single precursor, Fe 3(CH3COO)6(OH)2CH3COO, in a closed reactor at 700 °C in an inert atmosphere produced ferromagnetic Fe3O4 octahedra without using solvent or catalyst. The octahedral shape with the 6-10 μm diameter of Fe3O4 is realized using field emission scanning electron microscope, and the composition, with an attached energy dispersive X-ray analyzer. The single-crystalline face-centered cubic structure of Fe3O4 octahedra is analyzed by X-ray diffraction measurements, further supported by Raman spectroscopy and transmission electron microscopy. The thermogravimetric analysis measured the amount of carbon present on the Fe3O 4 octahedra surfaces. The vibrating magnetometer corroborated ferromagnetic behavior of Fe3O4 octahedra with 150 Oe coercive force, 48 emu/g saturation magnetization, and 5 emu/g remnent magnetization.",

author = "Pol, \{Vilas G.\} and Daemen, \{Luke L.\} and Sven Vogel and George Chertkov",

year = "2010",

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doi = "10.1021/ie9011062",

language = "English",

volume = "49",

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journal = "Industrial and Engineering Chemistry Research",

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publisher = "American Chemical Society",

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TY - JOUR

T1 - Solvent-free fabrication of ferromagnetic fe3o4 octahedra

AU - Pol, Vilas G.

AU - Daemen, Luke L.

AU - Vogel, Sven

AU - Chertkov, George

PY - 2010/1/20

Y1 - 2010/1/20

N2 - The controlled thermolysis of a presynthesized single precursor, Fe 3(CH3COO)6(OH)2CH3COO, in a closed reactor at 700 °C in an inert atmosphere produced ferromagnetic Fe3O4 octahedra without using solvent or catalyst. The octahedral shape with the 6-10 μm diameter of Fe3O4 is realized using field emission scanning electron microscope, and the composition, with an attached energy dispersive X-ray analyzer. The single-crystalline face-centered cubic structure of Fe3O4 octahedra is analyzed by X-ray diffraction measurements, further supported by Raman spectroscopy and transmission electron microscopy. The thermogravimetric analysis measured the amount of carbon present on the Fe3O 4 octahedra surfaces. The vibrating magnetometer corroborated ferromagnetic behavior of Fe3O4 octahedra with 150 Oe coercive force, 48 emu/g saturation magnetization, and 5 emu/g remnent magnetization.

AB - The controlled thermolysis of a presynthesized single precursor, Fe 3(CH3COO)6(OH)2CH3COO, in a closed reactor at 700 °C in an inert atmosphere produced ferromagnetic Fe3O4 octahedra without using solvent or catalyst. The octahedral shape with the 6-10 μm diameter of Fe3O4 is realized using field emission scanning electron microscope, and the composition, with an attached energy dispersive X-ray analyzer. The single-crystalline face-centered cubic structure of Fe3O4 octahedra is analyzed by X-ray diffraction measurements, further supported by Raman spectroscopy and transmission electron microscopy. The thermogravimetric analysis measured the amount of carbon present on the Fe3O 4 octahedra surfaces. The vibrating magnetometer corroborated ferromagnetic behavior of Fe3O4 octahedra with 150 Oe coercive force, 48 emu/g saturation magnetization, and 5 emu/g remnent magnetization.

UR - https://www.scopus.com/pages/publications/75249107045

U2 - 10.1021/ie9011062

DO - 10.1021/ie9011062

M3 - Article

AN - SCOPUS:75249107045

SN - 0888-5885

VL - 49

SP - 920

EP - 924

JO - Industrial and Engineering Chemistry Research

JF - Industrial and Engineering Chemistry Research

IS - 2

ER -

Solvent-free fabrication of ferromagnetic fe₃o₄ octahedra

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