Solvation of Calix[4]arene-bis-crown-6 molecules

Jeffrey C. Bryan; Tianniu Chen; Tatiana G. Levitskaia; Tamara J. Haverlock; Craig E. Barnes; Bruce A. Moyer

doi:10.1023/A:1016096203791

Solvation of Calix[4]arene-bis-crown-6 molecules

Jeffrey C. Bryan, Tianniu Chen, Tatiana G. Levitskaia, Tamara J. Haverlock, Craig E. Barnes, Bruce A. Moyer

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Single crystal X-ray diffraction analyses of calix[4]arene-bis-crown-6 (1) and calix[4]arene-bis-benzocrown-6·1,2-dichloroethane (2) are reported. These structures offer an opportunity to study the conformation of calix[4]arene-bis-crown-6 molecules in the absence of solvent, and when very weakly solvated. These structures exhibit different conformations of the crown ring, and limited flexibility of the calix[4]arene, but do not show solvent or crown inclusion in the calix[4]arene cavity. Comparisons to similar structures are made, and the implications for cesium binding are discussed.

Original language	English
Pages (from-to)	241-245
Number of pages	5
Journal	Journal of Inclusion Phenomena
Volume	42
Issue number	3-4
DOIs	https://doi.org/10.1023/A:1016096203791
State	Published - 2002

Funding

This research was sponsored by the Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences, U.S. Department of Energy, under contract DE-AC05-00OR22725 with Oak Ridge National Laboratory, managed and operated by UT-Battelle, LLC.

Keywords

Calixarene
Crown ether
Crystal structure
Solvation

Access to Document

10.1023/A:1016096203791

Cite this

@article{7cbca0e377f546ca884259fd70ca4632,

title = "Solvation of Calix[4]arene-bis-crown-6 molecules",

abstract = "Single crystal X-ray diffraction analyses of calix[4]arene-bis-crown-6 (1) and calix[4]arene-bis-benzocrown-6·1,2-dichloroethane (2) are reported. These structures offer an opportunity to study the conformation of calix[4]arene-bis-crown-6 molecules in the absence of solvent, and when very weakly solvated. These structures exhibit different conformations of the crown ring, and limited flexibility of the calix[4]arene, but do not show solvent or crown inclusion in the calix[4]arene cavity. Comparisons to similar structures are made, and the implications for cesium binding are discussed.",

keywords = "Calixarene, Crown ether, Crystal structure, Solvation",

author = "Bryan, \{Jeffrey C.\} and Tianniu Chen and Levitskaia, \{Tatiana G.\} and Haverlock, \{Tamara J.\} and Barnes, \{Craig E.\} and Moyer, \{Bruce A.\}",

year = "2002",

doi = "10.1023/A:1016096203791",

language = "English",

volume = "42",

pages = "241--245",

journal = "Journal of Inclusion Phenomena",

issn = "0923-0750",

publisher = "Springer",

number = "3-4",

}

TY - JOUR

T1 - Solvation of Calix[4]arene-bis-crown-6 molecules

AU - Bryan, Jeffrey C.

AU - Chen, Tianniu

AU - Levitskaia, Tatiana G.

AU - Haverlock, Tamara J.

AU - Barnes, Craig E.

AU - Moyer, Bruce A.

PY - 2002

Y1 - 2002

N2 - Single crystal X-ray diffraction analyses of calix[4]arene-bis-crown-6 (1) and calix[4]arene-bis-benzocrown-6·1,2-dichloroethane (2) are reported. These structures offer an opportunity to study the conformation of calix[4]arene-bis-crown-6 molecules in the absence of solvent, and when very weakly solvated. These structures exhibit different conformations of the crown ring, and limited flexibility of the calix[4]arene, but do not show solvent or crown inclusion in the calix[4]arene cavity. Comparisons to similar structures are made, and the implications for cesium binding are discussed.

AB - Single crystal X-ray diffraction analyses of calix[4]arene-bis-crown-6 (1) and calix[4]arene-bis-benzocrown-6·1,2-dichloroethane (2) are reported. These structures offer an opportunity to study the conformation of calix[4]arene-bis-crown-6 molecules in the absence of solvent, and when very weakly solvated. These structures exhibit different conformations of the crown ring, and limited flexibility of the calix[4]arene, but do not show solvent or crown inclusion in the calix[4]arene cavity. Comparisons to similar structures are made, and the implications for cesium binding are discussed.

KW - Calixarene

KW - Crown ether

KW - Crystal structure

KW - Solvation

UR - https://www.scopus.com/pages/publications/0346394775

U2 - 10.1023/A:1016096203791

DO - 10.1023/A:1016096203791

M3 - Article

AN - SCOPUS:0346394775

SN - 0923-0750

VL - 42

SP - 241

EP - 245

JO - Journal of Inclusion Phenomena

JF - Journal of Inclusion Phenomena

IS - 3-4

ER -

Solvation of Calix[4]arene-bis-crown-6 molecules

Abstract

Funding

Keywords

Access to Document

Other files and links

Fingerprint

Cite this