Soluble porous coordination polymers by mechanochemistry: From metal-containing films/membranes to active catalysts for aerobic oxidation

Pengfei Zhang; Haiying Li; Gabriel M. Veith; Sheng Dai

doi:10.1002/adma.201403299

Soluble porous coordination polymers by mechanochemistry: From metal-containing films/membranes to active catalysts for aerobic oxidation

Pengfei Zhang
, Haiying Li
, Gabriel M. Veith
, Sheng Dai

Research output: Contribution to journal › Article › peer-review

93 Scopus citations

Abstract

Soluble porous coordination polymers from mechanochemical synthesis are presented through a coordination polymerization between highly contorted, rigid tetraphenol and a broad variety of transition metal ions. These polymers can be easily cast as metal-containing films or freestanding membranes. Importantly, as-made coordination polymers are highly active and stable in the aerobic oxidation of allylic C H bonds.

Original language	English
Pages (from-to)	234-239
Number of pages	6
Journal	Advanced Materials
Volume	27
Issue number	2
DOIs	https://doi.org/10.1002/adma.201403299
State	Published - Jan 14 2015

Keywords

Mechanochemistry
O-donor ligands
Polymers of intrinsic microporosity
Porous coordination polymers
Porous thin films

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title = "Soluble porous coordination polymers by mechanochemistry: From metal-containing films/membranes to active catalysts for aerobic oxidation",

abstract = "Soluble porous coordination polymers from mechanochemical synthesis are presented through a coordination polymerization between highly contorted, rigid tetraphenol and a broad variety of transition metal ions. These polymers can be easily cast as metal-containing films or freestanding membranes. Importantly, as-made coordination polymers are highly active and stable in the aerobic oxidation of allylic C H bonds.",

keywords = "Mechanochemistry, O-donor ligands, Polymers of intrinsic microporosity, Porous coordination polymers, Porous thin films",

author = "Pengfei Zhang and Haiying Li and Veith, \{Gabriel M.\} and Sheng Dai",

note = "Publisher Copyright: {\textcopyright} 2014 WILEY-VCH Verlag GmbH \& Co. KGaA.",

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AU - Zhang, Pengfei

AU - Li, Haiying

AU - Veith, Gabriel M.

AU - Dai, Sheng

PY - 2015/1/14

Y1 - 2015/1/14

N2 - Soluble porous coordination polymers from mechanochemical synthesis are presented through a coordination polymerization between highly contorted, rigid tetraphenol and a broad variety of transition metal ions. These polymers can be easily cast as metal-containing films or freestanding membranes. Importantly, as-made coordination polymers are highly active and stable in the aerobic oxidation of allylic C H bonds.

AB - Soluble porous coordination polymers from mechanochemical synthesis are presented through a coordination polymerization between highly contorted, rigid tetraphenol and a broad variety of transition metal ions. These polymers can be easily cast as metal-containing films or freestanding membranes. Importantly, as-made coordination polymers are highly active and stable in the aerobic oxidation of allylic C H bonds.

KW - Mechanochemistry

KW - O-donor ligands

KW - Polymers of intrinsic microporosity

KW - Porous coordination polymers

KW - Porous thin films

UR - https://www.scopus.com/pages/publications/84920749768

U2 - 10.1002/adma.201403299

DO - 10.1002/adma.201403299

M3 - Article

AN - SCOPUS:84920749768

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JO - Advanced Materials

JF - Advanced Materials

IS - 2

ER -

Soluble porous coordination polymers by mechanochemistry: From metal-containing films/membranes to active catalysts for aerobic oxidation

Abstract

Keywords

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