Solid-State Synthesis of Conjugated Nanoporous Polycarbazoles

Xiang Zhu; Chengcheng Tian; Tian Jin; Katie L. Browning; Robert L. Sacci; Gabriel M. Veith; Sheng Dai

doi:10.1021/acsmacrolett.7b00480

Solid-State Synthesis of Conjugated Nanoporous Polycarbazoles

Xiang Zhu, Chengcheng Tian, Tian Jin, Katie L. Browning, Robert L. Sacci, Gabriel M. Veith, Sheng Dai

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

A novel solid-state synthetic approach has been developed for the generation of conjugated nanoporous polymer networks. Using mechanochemical-assisted oxidative coupling polymerization, we demonstrated a rapid and solvent-free synthesis of conjugated polycarbazoles with high porosities and promising CO₂ storage abilities. This innovative approach constitutes a new direction for the development of novel nanoporous polymer frameworks through sustainable solid-state assembly pathways, and may open up new possibilities for the rational design and synthesis of nanoporous materials for carbon capture.

Original language	English
Pages (from-to)	1056-1059
Number of pages	4
Journal	ACS Macro Letters
Volume	6
Issue number	10
DOIs	https://doi.org/10.1021/acsmacrolett.7b00480
State	Published - Oct 17 2017

Funding

The research was supported financially by the Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences, U.S. Department of Energy. G.M.V., K.L.B., and R.L.S. were supported by the Department of Energy Office of Science, Division of Materials Sciences and Engineering.

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abstract = "A novel solid-state synthetic approach has been developed for the generation of conjugated nanoporous polymer networks. Using mechanochemical-assisted oxidative coupling polymerization, we demonstrated a rapid and solvent-free synthesis of conjugated polycarbazoles with high porosities and promising CO2 storage abilities. This innovative approach constitutes a new direction for the development of novel nanoporous polymer frameworks through sustainable solid-state assembly pathways, and may open up new possibilities for the rational design and synthesis of nanoporous materials for carbon capture.",

author = "Xiang Zhu and Chengcheng Tian and Tian Jin and Browning, {Katie L.} and Sacci, {Robert L.} and Veith, {Gabriel M.} and Sheng Dai",

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AU - Jin, Tian

AU - Browning, Katie L.

AU - Sacci, Robert L.

AU - Veith, Gabriel M.

AU - Dai, Sheng

PY - 2017/10/17

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AB - A novel solid-state synthetic approach has been developed for the generation of conjugated nanoporous polymer networks. Using mechanochemical-assisted oxidative coupling polymerization, we demonstrated a rapid and solvent-free synthesis of conjugated polycarbazoles with high porosities and promising CO2 storage abilities. This innovative approach constitutes a new direction for the development of novel nanoporous polymer frameworks through sustainable solid-state assembly pathways, and may open up new possibilities for the rational design and synthesis of nanoporous materials for carbon capture.

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Solid-State Synthesis of Conjugated Nanoporous Polycarbazoles

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