Sodium insertion in carboxylate based materials and their application in 3.6 v full sodium cells

Ali Abouimrane; Wei Weng; Hussameldin Eltayeb; Yanjie Cui; Jens Niklas; Oleg Poluektov; Khalil Amine

doi:10.1039/c2ee22864e

Sodium insertion in carboxylate based materials and their application in 3.6 v full sodium cells

Ali Abouimrane, Wei Weng, Hussameldin Eltayeb, Yanjie Cui, Jens Niklas, Oleg Poluektov, Khalil Amine

Research output: Contribution to journal › Article › peer-review

247 Scopus citations

Abstract

The sodium battery has the potential to be the next generation rechargeable system which utilizes cheaper and more abundant sodium material but affords nearly the same power as lithium batteries. One of the key barriers for the sodium battery is the lack of stable anode materials which can insert sodium ions reversibly at relatively low potential. This contribution reports the sodium insertion in a series of organic carboxylate based materials: (C ₈H ₄Na ₂O ₄), (C ₈H ₆O ₄), (C ₈H ₅NaO ₄), (C ₈Na ₂F ₄O ₄), (C ₁₀H ₂Na ₄O ₈), (C ₁₄H ₄O ₆) and (C ₁₄H ₄Na ₄O ₈) at low voltage (below 0.6 V vs. Na/Na ⁺). These organic anode materials can insert reversibly up to 2 Na per molecule with good cycleability. The Na insertion mechanism was proposed and 3.6 V full sodium batteries were made and cycled reversibly at room temperature and at 55°C.

Original language	English
Pages (from-to)	9632-9638
Number of pages	7
Journal	Energy and Environmental Science
Volume	5
Issue number	11
DOIs	https://doi.org/10.1039/c2ee22864e
State	Published - Nov 2012
Externally published	Yes

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title = "Sodium insertion in carboxylate based materials and their application in 3.6 v full sodium cells",

abstract = "The sodium battery has the potential to be the next generation rechargeable system which utilizes cheaper and more abundant sodium material but affords nearly the same power as lithium batteries. One of the key barriers for the sodium battery is the lack of stable anode materials which can insert sodium ions reversibly at relatively low potential. This contribution reports the sodium insertion in a series of organic carboxylate based materials: (C 8H 4Na 2O 4), (C 8H 6O 4), (C 8H 5NaO 4), (C 8Na 2F 4O 4), (C 10H 2Na 4O 8), (C 14H 4O 6) and (C 14H 4Na 4O 8) at low voltage (below 0.6 V vs. Na/Na +). These organic anode materials can insert reversibly up to 2 Na per molecule with good cycleability. The Na insertion mechanism was proposed and 3.6 V full sodium batteries were made and cycled reversibly at room temperature and at 55°C.",

author = "Ali Abouimrane and Wei Weng and Hussameldin Eltayeb and Yanjie Cui and Jens Niklas and Oleg Poluektov and Khalil Amine",

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AU - Abouimrane, Ali

AU - Weng, Wei

AU - Eltayeb, Hussameldin

AU - Cui, Yanjie

AU - Niklas, Jens

AU - Poluektov, Oleg

AU - Amine, Khalil

PY - 2012/11

Y1 - 2012/11

N2 - The sodium battery has the potential to be the next generation rechargeable system which utilizes cheaper and more abundant sodium material but affords nearly the same power as lithium batteries. One of the key barriers for the sodium battery is the lack of stable anode materials which can insert sodium ions reversibly at relatively low potential. This contribution reports the sodium insertion in a series of organic carboxylate based materials: (C 8H 4Na 2O 4), (C 8H 6O 4), (C 8H 5NaO 4), (C 8Na 2F 4O 4), (C 10H 2Na 4O 8), (C 14H 4O 6) and (C 14H 4Na 4O 8) at low voltage (below 0.6 V vs. Na/Na +). These organic anode materials can insert reversibly up to 2 Na per molecule with good cycleability. The Na insertion mechanism was proposed and 3.6 V full sodium batteries were made and cycled reversibly at room temperature and at 55°C.

AB - The sodium battery has the potential to be the next generation rechargeable system which utilizes cheaper and more abundant sodium material but affords nearly the same power as lithium batteries. One of the key barriers for the sodium battery is the lack of stable anode materials which can insert sodium ions reversibly at relatively low potential. This contribution reports the sodium insertion in a series of organic carboxylate based materials: (C 8H 4Na 2O 4), (C 8H 6O 4), (C 8H 5NaO 4), (C 8Na 2F 4O 4), (C 10H 2Na 4O 8), (C 14H 4O 6) and (C 14H 4Na 4O 8) at low voltage (below 0.6 V vs. Na/Na +). These organic anode materials can insert reversibly up to 2 Na per molecule with good cycleability. The Na insertion mechanism was proposed and 3.6 V full sodium batteries were made and cycled reversibly at room temperature and at 55°C.

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JO - Energy and Environmental Science

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Sodium insertion in carboxylate based materials and their application in 3.6 v full sodium cells

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