Small-angle X-ray scattering from zirconium(IV) hydrous tetramers

L. M. Toth; J. S. Lin; L. K. Felker

doi:10.1021/j100161a028

Small-angle X-ray scattering from zirconium(IV) hydrous tetramers

L. M. Toth, J. S. Lin, L. K. Felker

National Isotope Development Center

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Abstract

Small-angle X-ray scattering (SAXS) data were collected for 0.035-1.0 M Zr(IV) in aqueous solution where the species present were hydroxyl-bridged tetramers. The scattering data were fitted to a cylindrical model with a radius of 4.8 Å and an aspect ratio of 2.3. Similar fits of the data to spherical and elliptical models were also tested. These SAXS data have provided corroborative evidence for the existence of tetrameric species in aqueous solution.

Original language	English
Pages (from-to)	3106-3108
Number of pages	3
Journal	Journal of Physical Chemistry
Volume	95
Issue number	8
DOIs	https://doi.org/10.1021/j100161a028
State	Published - 1991

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title = "Small-angle X-ray scattering from zirconium(IV) hydrous tetramers",

abstract = "Small-angle X-ray scattering (SAXS) data were collected for 0.035-1.0 M Zr(IV) in aqueous solution where the species present were hydroxyl-bridged tetramers. The scattering data were fitted to a cylindrical model with a radius of 4.8 {\AA} and an aspect ratio of 2.3. Similar fits of the data to spherical and elliptical models were also tested. These SAXS data have provided corroborative evidence for the existence of tetrameric species in aqueous solution.",

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year = "1991",

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AU - Toth, L. M.

AU - Lin, J. S.

AU - Felker, L. K.

PY - 1991

Y1 - 1991

N2 - Small-angle X-ray scattering (SAXS) data were collected for 0.035-1.0 M Zr(IV) in aqueous solution where the species present were hydroxyl-bridged tetramers. The scattering data were fitted to a cylindrical model with a radius of 4.8 Å and an aspect ratio of 2.3. Similar fits of the data to spherical and elliptical models were also tested. These SAXS data have provided corroborative evidence for the existence of tetrameric species in aqueous solution.

AB - Small-angle X-ray scattering (SAXS) data were collected for 0.035-1.0 M Zr(IV) in aqueous solution where the species present were hydroxyl-bridged tetramers. The scattering data were fitted to a cylindrical model with a radius of 4.8 Å and an aspect ratio of 2.3. Similar fits of the data to spherical and elliptical models were also tested. These SAXS data have provided corroborative evidence for the existence of tetrameric species in aqueous solution.

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DO - 10.1021/j100161a028

M3 - Article

AN - SCOPUS:0001699534

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SP - 3106

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JO - Journal of Physical Chemistry

JF - Journal of Physical Chemistry

IS - 8

ER -

Small-angle X-ray scattering from zirconium(IV) hydrous tetramers

Abstract

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