Size controlled mechanochemical synthesis of ZrSi2

David Restrepo; Sandra M. Hick; Carolin Griebel; Juan Alarcón; Kyle Giesler; Yan Chen; Nina Orlovskaya; Richard G. Blair

doi:10.1039/c2cc36323b

Size controlled mechanochemical synthesis of ZrSi₂

David Restrepo
, Sandra M. Hick
, Carolin Griebel
, Juan Alarcón
, Kyle Giesler
, Yan Chen
, Nina Orlovskaya
, Richard G. Blair

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

Mechanochemical metathesis reactions were utilized to synthesize nanocrystalline ZrSi₂ ranging from 9–30 nm in size. Size was controlled through dilution with CaCl₂. A linear relationship was found between diluent concentration and crystallite size. Unlike typical self-propagating metathesis reactions, this reaction did not self-propagate, requiring the input of mechanical energy.

Original language	English
Pages (from-to)	707-709
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	7
DOIs	https://doi.org/10.1039/c2cc36323b
State	Published - 2013
Externally published	Yes

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title = "Size controlled mechanochemical synthesis of ZrSi2",

abstract = "Mechanochemical metathesis reactions were utilized to synthesize nanocrystalline ZrSi2 ranging from 9–30 nm in size. Size was controlled through dilution with CaCl2. A linear relationship was found between diluent concentration and crystallite size. Unlike typical self-propagating metathesis reactions, this reaction did not self-propagate, requiring the input of mechanical energy.",

author = "David Restrepo and Hick, \{Sandra M.\} and Carolin Griebel and Juan Alarc{\'o}n and Kyle Giesler and Yan Chen and Nina Orlovskaya and Blair, \{Richard G.\}",

year = "2013",

doi = "10.1039/c2cc36323b",

language = "English",

volume = "49",

pages = "707--709",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Size controlled mechanochemical synthesis of ZrSi2

AU - Restrepo, David

AU - Hick, Sandra M.

AU - Griebel, Carolin

AU - Alarcón, Juan

AU - Giesler, Kyle

AU - Chen, Yan

AU - Orlovskaya, Nina

AU - Blair, Richard G.

PY - 2013

Y1 - 2013

N2 - Mechanochemical metathesis reactions were utilized to synthesize nanocrystalline ZrSi2 ranging from 9–30 nm in size. Size was controlled through dilution with CaCl2. A linear relationship was found between diluent concentration and crystallite size. Unlike typical self-propagating metathesis reactions, this reaction did not self-propagate, requiring the input of mechanical energy.

AB - Mechanochemical metathesis reactions were utilized to synthesize nanocrystalline ZrSi2 ranging from 9–30 nm in size. Size was controlled through dilution with CaCl2. A linear relationship was found between diluent concentration and crystallite size. Unlike typical self-propagating metathesis reactions, this reaction did not self-propagate, requiring the input of mechanical energy.

UR - https://www.scopus.com/pages/publications/84871808224

U2 - 10.1039/c2cc36323b

DO - 10.1039/c2cc36323b

M3 - Article

AN - SCOPUS:84871808224

SN - 1359-7345

VL - 49

SP - 707

EP - 709

JO - Chemical Communications

JF - Chemical Communications

IS - 7

ER -

Size controlled mechanochemical synthesis of ZrSi₂

Abstract

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