Single crystal structures of the new vanadates CuMgVO4 and AgMgVO4

Hamdi Ben Yahia; Masahiro Shikano; Rachid Essehli; Ilias Belharouak

doi:10.1016/j.matchemphys.2016.04.079

Single crystal structures of the new vanadates CuMgVO₄ and AgMgVO₄

Hamdi Ben Yahia, Masahiro Shikano, Rachid Essehli, Ilias Belharouak

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The new compounds CuMgVO₄ and AgMgVO₄ have been synthesized by a solid state reaction route. Their crystal structures were determined from single-crystal X-ray diffraction data. CuMgVO₄ crystallizes with Na₂CrO₄-type structure with space group Cmcm, a = 5.6932 (10), b = 8.7055 (15), c = 6.2789 (10) Å, V = 311.20 (9) Å³, and Z = 4, whereas AgMgVO₄ crystallizes in the maricite-type structure with space group Pnma, a = 9.4286 (14), b = 6.7465 (10), c = 5.3360 (8) Å, V = 339.42 (9) Å³, and Z = 4. Both structures of CuMgVO₄, and AgMgVO₄ contain MgO₄ chains made up of edge-sharing MgO₆ octahedra. In CuMgVO₄ the MgO₄ chains are interconnected through CuVO₄ double chains made up of VO₄ and CuO₄ tetrahedra sharing corners and edges, however in AgMgVO₄ the chains are interlinked by the VO₄ and AgO₄ tetrahedra sharing only corners.

Original language	English
Pages (from-to)	128-132
Number of pages	5
Journal	Materials Chemistry and Physics
Volume	178
DOIs	https://doi.org/10.1016/j.matchemphys.2016.04.079
State	Published - 2016
Externally published	Yes

Funding

Part of this work was financially supported by the Japan Society for the Promotion of Science (JSPS) KAKENHI Grant-in-Aid for JSPS Fellows Grant Number 24·02506 .

Funders	Funder number
Japan Society for the Promotion of Science	02506

Keywords

Crystal growth
Crystal structure
Inorganic compounds
Oxides
Phase transitions

Access to Document

10.1016/j.matchemphys.2016.04.079

Cite this

@article{cd915c48f8d443728e0a91a5dc5aaa23,

title = "Single crystal structures of the new vanadates CuMgVO4 and AgMgVO4",

abstract = "The new compounds CuMgVO4 and AgMgVO4 have been synthesized by a solid state reaction route. Their crystal structures were determined from single-crystal X-ray diffraction data. CuMgVO4 crystallizes with Na2CrO4-type structure with space group Cmcm, a = 5.6932 (10), b = 8.7055 (15), c = 6.2789 (10) {\AA}, V = 311.20 (9) {\AA}3, and Z = 4, whereas AgMgVO4 crystallizes in the maricite-type structure with space group Pnma, a = 9.4286 (14), b = 6.7465 (10), c = 5.3360 (8) {\AA}, V = 339.42 (9) {\AA}3, and Z = 4. Both structures of CuMgVO4, and AgMgVO4 contain MgO4 chains made up of edge-sharing MgO6 octahedra. In CuMgVO4 the MgO4 chains are interconnected through CuVO4 double chains made up of VO4 and CuO4 tetrahedra sharing corners and edges, however in AgMgVO4 the chains are interlinked by the VO4 and AgO4 tetrahedra sharing only corners.",

keywords = "Crystal growth, Crystal structure, Inorganic compounds, Oxides, Phase transitions",

author = "{Ben Yahia}, Hamdi and Masahiro Shikano and Rachid Essehli and Ilias Belharouak",

note = "Publisher Copyright: {\textcopyright} 2016 Elsevier B.V.",

year = "2016",

doi = "10.1016/j.matchemphys.2016.04.079",

language = "English",

volume = "178",

pages = "128--132",

journal = "Materials Chemistry and Physics",

issn = "0254-0584",

publisher = "Elsevier",

}

TY - JOUR

T1 - Single crystal structures of the new vanadates CuMgVO4 and AgMgVO4

AU - Ben Yahia, Hamdi

AU - Shikano, Masahiro

AU - Essehli, Rachid

AU - Belharouak, Ilias

PY - 2016

Y1 - 2016

N2 - The new compounds CuMgVO4 and AgMgVO4 have been synthesized by a solid state reaction route. Their crystal structures were determined from single-crystal X-ray diffraction data. CuMgVO4 crystallizes with Na2CrO4-type structure with space group Cmcm, a = 5.6932 (10), b = 8.7055 (15), c = 6.2789 (10) Å, V = 311.20 (9) Å3, and Z = 4, whereas AgMgVO4 crystallizes in the maricite-type structure with space group Pnma, a = 9.4286 (14), b = 6.7465 (10), c = 5.3360 (8) Å, V = 339.42 (9) Å3, and Z = 4. Both structures of CuMgVO4, and AgMgVO4 contain MgO4 chains made up of edge-sharing MgO6 octahedra. In CuMgVO4 the MgO4 chains are interconnected through CuVO4 double chains made up of VO4 and CuO4 tetrahedra sharing corners and edges, however in AgMgVO4 the chains are interlinked by the VO4 and AgO4 tetrahedra sharing only corners.

AB - The new compounds CuMgVO4 and AgMgVO4 have been synthesized by a solid state reaction route. Their crystal structures were determined from single-crystal X-ray diffraction data. CuMgVO4 crystallizes with Na2CrO4-type structure with space group Cmcm, a = 5.6932 (10), b = 8.7055 (15), c = 6.2789 (10) Å, V = 311.20 (9) Å3, and Z = 4, whereas AgMgVO4 crystallizes in the maricite-type structure with space group Pnma, a = 9.4286 (14), b = 6.7465 (10), c = 5.3360 (8) Å, V = 339.42 (9) Å3, and Z = 4. Both structures of CuMgVO4, and AgMgVO4 contain MgO4 chains made up of edge-sharing MgO6 octahedra. In CuMgVO4 the MgO4 chains are interconnected through CuVO4 double chains made up of VO4 and CuO4 tetrahedra sharing corners and edges, however in AgMgVO4 the chains are interlinked by the VO4 and AgO4 tetrahedra sharing only corners.

KW - Crystal growth

KW - Crystal structure

KW - Inorganic compounds

KW - Oxides

KW - Phase transitions

UR - http://www.scopus.com/inward/record.url?scp=84964898033&partnerID=8YFLogxK

U2 - 10.1016/j.matchemphys.2016.04.079

DO - 10.1016/j.matchemphys.2016.04.079

M3 - Article

AN - SCOPUS:84964898033

SN - 0254-0584

VL - 178

SP - 128

EP - 132

JO - Materials Chemistry and Physics

JF - Materials Chemistry and Physics

ER -