Single-Atom Catalysis: An Analogy between Heterogeneous and Homogeneous Catalysts

Simuck F. Yuk; Greg Collinge; Manh Thuong Nguyen; Mal Soon Lee; Vassiliki Alexandra Glezakou; Roger Rousseau

doi:10.1021/bk-2020-1360.ch001

Single-Atom Catalysis: An Analogy between Heterogeneous and Homogeneous Catalysts

Simuck F. Yuk, Greg Collinge, Manh Thuong Nguyen, Mal Soon Lee, Vassiliki Alexandra Glezakou, Roger Rousseau

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

4 Scopus citations

Abstract

In recent years, enormous efforts have been devoted to improving the atom efficiency of metal catalysts by decreasing the size of metal particles to the limit of isolated atoms in heterogeneous catalysis, termed single-atom catalysts (SACs). In addition to being atom-efficient, these SACs are increasingly gaining attention because of the unique reactivity and selectivity they exhibit in industrially relevant reactions, including both oxidation and hydrogenation reactions. Clear parallels can be drawn between heterogeneous SACs and their analogous homogeneous catalysts. In this chapter, we highlight SACs that demonstrate this relationship and report on relevant, recent developments in the field of single-atom catalysis.

Original language	English
Title of host publication	ACS Symposium Series
Editors	Putla Sudarsanam, Lakhveer Singh
Publisher	American Chemical Society
Pages	1-15
Number of pages	15
DOIs	https://doi.org/10.1021/bk-2020-1360.ch001
State	Published - 2020
Externally published	Yes

Publication series

Name	ACS Symposium Series
Volume	1360
ISSN (Print)	0097-6156
ISSN (Electronic)	1947-5918

Funding

This work was supported by the U.S. Department of Energy (DOE), Office of Science, Basic Energy Sciences, Chemical Sciences, Geosciences, and Biosciences Division. Pacific Northwest National Laboratory is operated by Battelle for DOE under Contract DE-AC05-76RL01830.

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10.1021/bk-2020-1360.ch001

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abstract = "In recent years, enormous efforts have been devoted to improving the atom efficiency of metal catalysts by decreasing the size of metal particles to the limit of isolated atoms in heterogeneous catalysis, termed single-atom catalysts (SACs). In addition to being atom-efficient, these SACs are increasingly gaining attention because of the unique reactivity and selectivity they exhibit in industrially relevant reactions, including both oxidation and hydrogenation reactions. Clear parallels can be drawn between heterogeneous SACs and their analogous homogeneous catalysts. In this chapter, we highlight SACs that demonstrate this relationship and report on relevant, recent developments in the field of single-atom catalysis.",

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Single-Atom Catalysis: An Analogy between Heterogeneous and Homogeneous Catalysts. / Yuk, Simuck F.; Collinge, Greg; Nguyen, Manh Thuong et al.
ACS Symposium Series. ed. / Putla Sudarsanam; Lakhveer Singh. American Chemical Society, 2020. p. 1-15 (ACS Symposium Series; Vol. 1360).

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

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Single-Atom Catalysis: An Analogy between Heterogeneous and Homogeneous Catalysts

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