Seven-coordinate anion complex with a tren-based urea: Binding discrepancy of hydrogen sulfate in solid and solution states

Avijit Pramanik; Bethtrice Thompson; Trina Hayes; Kimberly Tucker; Douglas R. Powell; Peter V. Bonnesen; Erick D. Ellis; Ken S. Lee; Hongtao Yu; Md Alamgir Hossain

doi:10.1039/c1ob05052d

Seven-coordinate anion complex with a tren-based urea: Binding discrepancy of hydrogen sulfate in solid and solution states

Avijit Pramanik, Bethtrice Thompson, Trina Hayes, Kimberly Tucker, Douglas R. Powell, Peter V. Bonnesen, Erick D. Ellis, Ken S. Lee, Hongtao Yu, Md Alamgir Hossain

Macromolecular Nanomaterials

Research output: Contribution to journal › Article › peer-review

44 Scopus citations

Abstract

Structural characterization of a hydrogen sulfate complex with a tren-based urea suggests that the anion is coordinated with six NH⋯O bonds (d _N⋯ _O = 2.857 (3) to 3.092 (3) Å) and one OH⋯O bond (d _O⋯ _O = 2.57 (2) Å) from three receptors; however, in solution the anion is bound within the pseudo-cavity of one receptor.

Original language	English
Pages (from-to)	4444-4447
Number of pages	4
Journal	Organic and Biomolecular Chemistry
Volume	9
Issue number	12
DOIs	https://doi.org/10.1039/c1ob05052d
State	Published - Jun 21 2011

Access to Document

10.1039/c1ob05052d

Cite this

@article{5a25e0e69e1942139dcd2e5076137237,

title = "Seven-coordinate anion complex with a tren-based urea: Binding discrepancy of hydrogen sulfate in solid and solution states",

abstract = "Structural characterization of a hydrogen sulfate complex with a tren-based urea suggests that the anion is coordinated with six NH⋯O bonds (d N⋯ O = 2.857 (3) to 3.092 (3) {\AA}) and one OH⋯O bond (d O⋯ O = 2.57 (2) {\AA}) from three receptors; however, in solution the anion is bound within the pseudo-cavity of one receptor.",

author = "Avijit Pramanik and Bethtrice Thompson and Trina Hayes and Kimberly Tucker and Powell, {Douglas R.} and Bonnesen, {Peter V.} and Ellis, {Erick D.} and Lee, {Ken S.} and Hongtao Yu and Hossain, {Md Alamgir}",

year = "2011",

month = jun,

day = "21",

doi = "10.1039/c1ob05052d",

language = "English",

volume = "9",

pages = "4444--4447",

journal = "Organic and Biomolecular Chemistry",

issn = "1477-0520",

publisher = "Royal Society of Chemistry",

number = "12",

}

TY - JOUR

T1 - Seven-coordinate anion complex with a tren-based urea

T2 - Binding discrepancy of hydrogen sulfate in solid and solution states

AU - Pramanik, Avijit

AU - Thompson, Bethtrice

AU - Hayes, Trina

AU - Tucker, Kimberly

AU - Powell, Douglas R.

AU - Bonnesen, Peter V.

AU - Ellis, Erick D.

AU - Lee, Ken S.

AU - Yu, Hongtao

AU - Hossain, Md Alamgir

PY - 2011/6/21

Y1 - 2011/6/21

N2 - Structural characterization of a hydrogen sulfate complex with a tren-based urea suggests that the anion is coordinated with six NH⋯O bonds (d N⋯ O = 2.857 (3) to 3.092 (3) Å) and one OH⋯O bond (d O⋯ O = 2.57 (2) Å) from three receptors; however, in solution the anion is bound within the pseudo-cavity of one receptor.

AB - Structural characterization of a hydrogen sulfate complex with a tren-based urea suggests that the anion is coordinated with six NH⋯O bonds (d N⋯ O = 2.857 (3) to 3.092 (3) Å) and one OH⋯O bond (d O⋯ O = 2.57 (2) Å) from three receptors; however, in solution the anion is bound within the pseudo-cavity of one receptor.

UR - http://www.scopus.com/inward/record.url?scp=79958004773&partnerID=8YFLogxK

U2 - 10.1039/c1ob05052d

DO - 10.1039/c1ob05052d

M3 - Article

C2 - 21424002

AN - SCOPUS:79958004773

SN - 1477-0520

VL - 9

SP - 4444

EP - 4447

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 12

ER -

Seven-coordinate anion complex with a tren-based urea: Binding discrepancy of hydrogen sulfate in solid and solution states

Abstract

Access to Document

Other files and links

Fingerprint

Cite this