Selective gas sorption within a dynamic metal-organic framework

Banglin Chen; Shengqian Ma; Eric J. Hurtado; Emil B. Lobkovsky; Chengdu Liang; Haoguo Zhu; Sheng Dai

doi:10.1021/ic7013573

Selective gas sorption within a dynamic metal-organic framework

Banglin Chen
, Shengqian Ma
, Eric J. Hurtado
, Emil B. Lobkovsky
, Chengdu Liang
, Haoguo Zhu
, Sheng Dai

Chemical Sciences Division

Research output: Contribution to journal › Article › peer-review

121 Scopus citations

Abstract

A microporous metal-organic framework 1 Co(NDC)(4,4′-Bipy) _0.5·G_x (NDC = 2,6-naphthalenedicarboxylate; 4,4′-Bipy = 4,4′-bipyridine; G = guest molecules) was synthesized and structurally characterized of a doubly interpenetrated primitive cubic net. To make use of the framework flexibility, 1 was activated at temperatures of 150 and 200°C to form 1a and 1b, respectively, exhibiting highly selective sorption behaviors of hydrogen over nitrogen-gas molecules.

Original language	English
Pages (from-to)	8705-8709
Number of pages	5
Journal	Inorganic Chemistry
Volume	46
Issue number	21
DOIs	https://doi.org/10.1021/ic7013573
State	Published - Oct 15 2007

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title = "Selective gas sorption within a dynamic metal-organic framework",

abstract = "A microporous metal-organic framework 1 Co(NDC)(4,4′-Bipy) 0.5·Gx (NDC = 2,6-naphthalenedicarboxylate; 4,4′-Bipy = 4,4′-bipyridine; G = guest molecules) was synthesized and structurally characterized of a doubly interpenetrated primitive cubic net. To make use of the framework flexibility, 1 was activated at temperatures of 150 and 200°C to form 1a and 1b, respectively, exhibiting highly selective sorption behaviors of hydrogen over nitrogen-gas molecules.",

author = "Banglin Chen and Shengqian Ma and Hurtado, \{Eric J.\} and Lobkovsky, \{Emil B.\} and Chengdu Liang and Haoguo Zhu and Sheng Dai",

year = "2007",

month = oct,

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doi = "10.1021/ic7013573",

language = "English",

volume = "46",

pages = "8705--8709",

journal = "Inorganic Chemistry",

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TY - JOUR

T1 - Selective gas sorption within a dynamic metal-organic framework

AU - Chen, Banglin

AU - Ma, Shengqian

AU - Hurtado, Eric J.

AU - Lobkovsky, Emil B.

AU - Liang, Chengdu

AU - Zhu, Haoguo

AU - Dai, Sheng

PY - 2007/10/15

Y1 - 2007/10/15

N2 - A microporous metal-organic framework 1 Co(NDC)(4,4′-Bipy) 0.5·Gx (NDC = 2,6-naphthalenedicarboxylate; 4,4′-Bipy = 4,4′-bipyridine; G = guest molecules) was synthesized and structurally characterized of a doubly interpenetrated primitive cubic net. To make use of the framework flexibility, 1 was activated at temperatures of 150 and 200°C to form 1a and 1b, respectively, exhibiting highly selective sorption behaviors of hydrogen over nitrogen-gas molecules.

AB - A microporous metal-organic framework 1 Co(NDC)(4,4′-Bipy) 0.5·Gx (NDC = 2,6-naphthalenedicarboxylate; 4,4′-Bipy = 4,4′-bipyridine; G = guest molecules) was synthesized and structurally characterized of a doubly interpenetrated primitive cubic net. To make use of the framework flexibility, 1 was activated at temperatures of 150 and 200°C to form 1a and 1b, respectively, exhibiting highly selective sorption behaviors of hydrogen over nitrogen-gas molecules.

UR - https://www.scopus.com/pages/publications/35648958737

U2 - 10.1021/ic7013573

DO - 10.1021/ic7013573

M3 - Article

AN - SCOPUS:35648958737

SN - 0020-1669

VL - 46

SP - 8705

EP - 8709

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 21

ER -

Selective gas sorption within a dynamic metal-organic framework

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