Seawater uranium sorbents: Preparation from a mesoporous copolymer initiator by atom-transfer radical polymerization

Yanfeng Yue; Richard T. Mayes; Jungseung Kim; Pasquale F. Fulvio; Xiao Guang Sun; Costas Tsouris; Jihua Chen; Suree Brown; Sheng Dai

doi:10.1002/anie.201307825

Seawater uranium sorbents: Preparation from a mesoporous copolymer initiator by atom-transfer radical polymerization

Yanfeng Yue
, Richard T. Mayes
, Jungseung Kim
, Pasquale F. Fulvio
, Xiao Guang Sun
, Costas Tsouris
, Jihua Chen
, Suree Brown
, Sheng Dai

Research output: Contribution to journal › Article › peer-review

241 Scopus citations

Abstract

From the sea to the reactor: Nanoporous template-free initiators for atom-transfer radical polymerization (ATRP) were synthesized with surface and framework initiator sites and tailorable pore structures. Polyacrylonitrile grown on one initiator was converted into polyamidoxime to generate a uranium sorbent for seawater extraction with a high uptake rate and capacity relative to those of nonwoven irradiation-grafted polyethylene-fiber composites.

Original language	English
Pages (from-to)	13458-13462
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	50
DOIs	https://doi.org/10.1002/anie.201307825
State	Published - Dec 9 2013

Keywords

amidoxime
atom-transfer radical polymerization
mesoporous copolymers
seawater
uranium extraction

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10.1002/anie.201307825

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title = "Seawater uranium sorbents: Preparation from a mesoporous copolymer initiator by atom-transfer radical polymerization",

abstract = "From the sea to the reactor: Nanoporous template-free initiators for atom-transfer radical polymerization (ATRP) were synthesized with surface and framework initiator sites and tailorable pore structures. Polyacrylonitrile grown on one initiator was converted into polyamidoxime to generate a uranium sorbent for seawater extraction with a high uptake rate and capacity relative to those of nonwoven irradiation-grafted polyethylene-fiber composites.",

keywords = "amidoxime, atom-transfer radical polymerization, mesoporous copolymers, seawater, uranium extraction",

author = "Yanfeng Yue and Mayes, \{Richard T.\} and Jungseung Kim and Fulvio, \{Pasquale F.\} and Sun, \{Xiao Guang\} and Costas Tsouris and Jihua Chen and Suree Brown and Sheng Dai",

year = "2013",

month = dec,

day = "9",

doi = "10.1002/anie.201307825",

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volume = "52",

pages = "13458--13462",

journal = "Angewandte Chemie - International Edition",

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TY - JOUR

T1 - Seawater uranium sorbents

T2 - Preparation from a mesoporous copolymer initiator by atom-transfer radical polymerization

AU - Yue, Yanfeng

AU - Mayes, Richard T.

AU - Kim, Jungseung

AU - Fulvio, Pasquale F.

AU - Sun, Xiao Guang

AU - Tsouris, Costas

AU - Chen, Jihua

AU - Brown, Suree

AU - Dai, Sheng

PY - 2013/12/9

Y1 - 2013/12/9

N2 - From the sea to the reactor: Nanoporous template-free initiators for atom-transfer radical polymerization (ATRP) were synthesized with surface and framework initiator sites and tailorable pore structures. Polyacrylonitrile grown on one initiator was converted into polyamidoxime to generate a uranium sorbent for seawater extraction with a high uptake rate and capacity relative to those of nonwoven irradiation-grafted polyethylene-fiber composites.

AB - From the sea to the reactor: Nanoporous template-free initiators for atom-transfer radical polymerization (ATRP) were synthesized with surface and framework initiator sites and tailorable pore structures. Polyacrylonitrile grown on one initiator was converted into polyamidoxime to generate a uranium sorbent for seawater extraction with a high uptake rate and capacity relative to those of nonwoven irradiation-grafted polyethylene-fiber composites.

KW - amidoxime

KW - atom-transfer radical polymerization

KW - mesoporous copolymers

KW - seawater

KW - uranium extraction

UR - https://www.scopus.com/pages/publications/84889659223

U2 - 10.1002/anie.201307825

DO - 10.1002/anie.201307825

M3 - Article

AN - SCOPUS:84889659223

SN - 1433-7851

VL - 52

SP - 13458

EP - 13462

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 50

ER -

Seawater uranium sorbents: Preparation from a mesoporous copolymer initiator by atom-transfer radical polymerization

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Keywords

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