Abstract
Excitons in semiconductors are usually noninteracting and behave like an ideal gas, but may condense to a strongly correlated liquid-like state, i.e., electron-hole liquid (EHL), at high density and appropriate temperature. An EHL is a macroscopic quantum state with exotic properties and represents the ultimate attainable charge excitation density in steady states. It bears great promise for a variety of fields such as ultra-high-power photonics and quantum science and technology. However, the condensation of gas-like excitons to an EHL has often been restricted to cryogenic temperatures, which significantly limits the prospect of EHLs for use in practical applications. Herein we demonstrate the formation of an EHL at room temperature in monolayer MoS2 by taking advantage of the monolayer's extraordinarily strong exciton binding energy. This work demonstrates the potential for the liquid-like state of charge excitations to be a useful platform for the studies of macroscopic quantum phenomena and the development of optoelectronic devices.
Original language | English |
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Pages (from-to) | 10351-10358 |
Number of pages | 8 |
Journal | ACS Nano |
Volume | 13 |
Issue number | 9 |
DOIs | |
State | Published - May 27 2019 |
Funding
This work was supported by the National Science Foundation under the grants ECCS-1508856 and DMR 1709934. The authors acknowledge the use of the Analytical Instrumentation Facility (AIF) at North Carolina State University, which is supported by the State of North Carolina and the National Science Foundation. Part of the Raman and PL work was conducted at the Center for Nanophase Materials Sciences, which is sponsored at Oak Ridge National Laboratory by the Scientific User Facilities Division, Office of Basic Energy Sciences, U.S. Department of Energy.
Funders | Funder number |
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Office of Basic Energy Sciences | |
Scientific User Facilities Division | |
National Science Foundation | ECCS-1508856, DMR 1709934, 1508856 |
U.S. Department of Energy | |
Oak Ridge National Laboratory | |
North Carolina State University |
Keywords
- TMDC
- electron-hole plasma
- exciton
- molybdenum disulfide
- phase transition
- transitional metal dichalcogenides