Roomerature Electron-Hole Liquid in Monolayer MoS2

Yiling Yu, Alexander W. Bataller, Robert Younts, Yifei Yu, Guoqing Li, Alexander A. Puretzky, David B. Geohegan, Kenan Gundogdu, Linyou Cao

Research output: Contribution to journalArticlepeer-review

56 Scopus citations

Abstract

Excitons in semiconductors are usually noninteracting and behave like an ideal gas, but may condense to a strongly correlated liquid-like state, i.e., electron-hole liquid (EHL), at high density and appropriate temperature. An EHL is a macroscopic quantum state with exotic properties and represents the ultimate attainable charge excitation density in steady states. It bears great promise for a variety of fields such as ultra-high-power photonics and quantum science and technology. However, the condensation of gas-like excitons to an EHL has often been restricted to cryogenic temperatures, which significantly limits the prospect of EHLs for use in practical applications. Herein we demonstrate the formation of an EHL at room temperature in monolayer MoS2 by taking advantage of the monolayer's extraordinarily strong exciton binding energy. This work demonstrates the potential for the liquid-like state of charge excitations to be a useful platform for the studies of macroscopic quantum phenomena and the development of optoelectronic devices.

Original languageEnglish
Pages (from-to)10351-10358
Number of pages8
JournalACS Nano
Volume13
Issue number9
DOIs
StatePublished - May 27 2019

Funding

This work was supported by the National Science Foundation under the grants ECCS-1508856 and DMR 1709934. The authors acknowledge the use of the Analytical Instrumentation Facility (AIF) at North Carolina State University, which is supported by the State of North Carolina and the National Science Foundation. Part of the Raman and PL work was conducted at the Center for Nanophase Materials Sciences, which is sponsored at Oak Ridge National Laboratory by the Scientific User Facilities Division, Office of Basic Energy Sciences, U.S. Department of Energy.

FundersFunder number
Office of Basic Energy Sciences
Scientific User Facilities Division
National Science FoundationECCS-1508856, DMR 1709934, 1508856
U.S. Department of Energy
Oak Ridge National Laboratory
North Carolina State University

    Keywords

    • TMDC
    • electron-hole plasma
    • exciton
    • molybdenum disulfide
    • phase transition
    • transitional metal dichalcogenides

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