Room temperature synthesis of high-entropy Prussian blue analogues

Wei Jiang; Tao Wang; Hao Chen; Xian Suo; Jiyuan Liang; Wenshuai Zhu; Huaming Li; Sheng Dai

doi:10.1016/j.nanoen.2020.105464

Room temperature synthesis of high-entropy Prussian blue analogues

Wei Jiang, Tao Wang, Hao Chen, Xian Suo, Jiyuan Liang, Wenshuai Zhu, Huaming Li, Sheng Dai

Research output: Contribution to journal › Article › peer-review

83 Scopus citations

Abstract

High-entropy Prussian blue analogues (HEPBAs) integrating the highly dispersed active sites of high-entropy materials with intrinsic 3D diffusion channels and the redox-active sites of Prussian blue analogues have great potential in electrochemical applications but have not been realized. In this work, a series of HEPBAs were successfully synthesized under room temperature combining mechanochemistry with wet chemistry for the first time.

Original language	English
Article number	105464
Journal	Nano Energy
Volume	79
DOIs	https://doi.org/10.1016/j.nanoen.2020.105464
State	Published - Jan 2021

Funding

This work was supported by the Fluid Interface Reactions, Structures and Transport (FIRST) Center , an Energy Frontier Research Center − US Department of Energy, Office of Science and Office of Basic Energy Sciences. Wei Jiang, Wenshuai Zhu, and Huaming Li were supported by the National Natural Science Foundation of China (No. 21978119 and 21722604 ). Wei Jiang appreciates the support of the Jiangsu Government Scholarship for oversea studies. This manuscript has been authored by UT-Battelle LLC under Contract No. DE-AC05–00OR22725 with DOE. The US government retains and the publisher, by accepting the article for publication, acknowledges that the US government retains a nonexclusive, paid-up, irrevocable, worldwide license to publish or reproduce the published form of this manuscript, or allow others to do so, for US government purposes. DOE will provide public access to these results of federally sponsored research in accordance with the DOE Public Access Plan ( http://energy.gov/downloads/doe-public-access-plan ). This work was supported by the Fluid Interface Reactions, Structures and Transport (FIRST) Center, an Energy Frontier Research Center ? US Department of Energy, Office of Science and Office of Basic Energy Sciences. Wei Jiang, Wenshuai Zhu, and Huaming Li were supported by the National Natural Science Foundation of China (No. 21978119 and 21722604). Wei Jiang appreciates the support of the Jiangsu Government Scholarship for oversea studies. This manuscript has been authored by UT-Battelle LLC under Contract No. DE-AC05?00OR22725 with DOE. The US government retains and the publisher, by accepting the article for publication, acknowledges that the US government retains a nonexclusive, paid-up, irrevocable, worldwide license to publish or reproduce the published form of this manuscript, or allow others to do so, for US government purposes. DOE will provide public access to these results of federally sponsored research in accordance with the DOE Public Access Plan (http://energy.gov/downloads/doe-public-access-plan).

Keywords

High-entropy Materials
Mechanochemistry
Prussian blue analogues
Supercapacitor

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10.1016/j.nanoen.2020.105464

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title = "Room temperature synthesis of high-entropy Prussian blue analogues",

abstract = "High-entropy Prussian blue analogues (HEPBAs) integrating the highly dispersed active sites of high-entropy materials with intrinsic 3D diffusion channels and the redox-active sites of Prussian blue analogues have great potential in electrochemical applications but have not been realized. In this work, a series of HEPBAs were successfully synthesized under room temperature combining mechanochemistry with wet chemistry for the first time.",

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author = "Wei Jiang and Tao Wang and Hao Chen and Xian Suo and Jiyuan Liang and Wenshuai Zhu and Huaming Li and Sheng Dai",

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AU - Li, Huaming

AU - Dai, Sheng

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N2 - High-entropy Prussian blue analogues (HEPBAs) integrating the highly dispersed active sites of high-entropy materials with intrinsic 3D diffusion channels and the redox-active sites of Prussian blue analogues have great potential in electrochemical applications but have not been realized. In this work, a series of HEPBAs were successfully synthesized under room temperature combining mechanochemistry with wet chemistry for the first time.

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Room temperature synthesis of high-entropy Prussian blue analogues

Abstract

Funding

Keywords

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