Room temperature reduction of multilayer graphene oxide film on a copper substrate: Penetration and participation of copper phase in redox reactions

Dmitry N. Voylov; Alexander L. Agapov; Alexei P. Sokolov; Yuri M. Shulga; Artem A. Arbuzov

doi:10.1016/j.carbon.2013.12.067

Room temperature reduction of multilayer graphene oxide film on a copper substrate: Penetration and participation of copper phase in redox reactions

Dmitry N. Voylov
, Alexander L. Agapov
, Alexei P. Sokolov
, Yuri M. Shulga
, Artem A. Arbuzov

Soft Materials and Membranes

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

A self-reduction of graphene oxide (GO) at room temperature after prolonged storage on a copper substrate is evidenced by decrease of oxygen content and a dramatic, 6 orders in magnitude, increase in dc conductivity. Experiments revealed that the stored GO film contains copper hydroxide phase embedded in the reduced GO structure.

Original language	English
Pages (from-to)	563-570
Number of pages	8
Journal	Carbon
Volume	69
DOIs	https://doi.org/10.1016/j.carbon.2013.12.067
State	Published - Apr 2014

Funding

This research was funded by the Russian Foundation of Basic Researches ( 11-03-01190-а ) and the Basic Research Program of the Presidium of RAS (#24). US team acknowledges partial financial support from the Division of Materials Science and Engineering, U.S. Department of Energy, Office of Basic Energy Sciences. These studies were performed in the framework of the US-Russia agreement on Collaboration in Clean Energy Technologies.

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title = "Room temperature reduction of multilayer graphene oxide film on a copper substrate: Penetration and participation of copper phase in redox reactions",

abstract = "A self-reduction of graphene oxide (GO) at room temperature after prolonged storage on a copper substrate is evidenced by decrease of oxygen content and a dramatic, 6 orders in magnitude, increase in dc conductivity. Experiments revealed that the stored GO film contains copper hydroxide phase embedded in the reduced GO structure.",

author = "Voylov, \{Dmitry N.\} and Agapov, \{Alexander L.\} and Sokolov, \{Alexei P.\} and Shulga, \{Yuri M.\} and Arbuzov, \{Artem A.\}",

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T2 - Penetration and participation of copper phase in redox reactions

AU - Voylov, Dmitry N.

AU - Agapov, Alexander L.

AU - Sokolov, Alexei P.

AU - Shulga, Yuri M.

AU - Arbuzov, Artem A.

PY - 2014/4

Y1 - 2014/4

N2 - A self-reduction of graphene oxide (GO) at room temperature after prolonged storage on a copper substrate is evidenced by decrease of oxygen content and a dramatic, 6 orders in magnitude, increase in dc conductivity. Experiments revealed that the stored GO film contains copper hydroxide phase embedded in the reduced GO structure.

AB - A self-reduction of graphene oxide (GO) at room temperature after prolonged storage on a copper substrate is evidenced by decrease of oxygen content and a dramatic, 6 orders in magnitude, increase in dc conductivity. Experiments revealed that the stored GO film contains copper hydroxide phase embedded in the reduced GO structure.

UR - https://www.scopus.com/pages/publications/84892819258

U2 - 10.1016/j.carbon.2013.12.067

DO - 10.1016/j.carbon.2013.12.067

M3 - Article

AN - SCOPUS:84892819258

SN - 0008-6223

VL - 69

SP - 563

EP - 570

JO - Carbon

JF - Carbon

ER -

Room temperature reduction of multilayer graphene oxide film on a copper substrate: Penetration and participation of copper phase in redox reactions

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