ROMPI-CDSA: Ring-opening metathesis polymerization-induced crystallization-driven self-assembly of metallo-block copolymers

Ye Sha; Md Anisur Rahman; Tianyu Zhu; Yujin Cha; C. Wayne McAlister; Chuanbing Tang

doi:10.1039/c9sc03056e

ROMPI-CDSA: Ring-opening metathesis polymerization-induced crystallization-driven self-assembly of metallo-block copolymers

Ye Sha, Md Anisur Rahman, Tianyu Zhu, Yujin Cha, C. Wayne McAlister, Chuanbing Tang

Research output: Contribution to journal › Article › peer-review

54 Scopus citations

Abstract

Polymerization-induced self-assembly (PISA) and crystallization-driven self-assembly (CDSA) are among the most prevailing methods for block copolymer self-assembly. Taking the merits of scalability of PISA and dimension control of CDSA, we report one-pot synchronous PISA and CDSA via ring-opening metathesis polymerization (ROMP) to prepare nano-objects based on a crystalline poly(ruthenocene) motif. We denote this self-assembly methodology as ROMPI-CDSA to enable a simple, yet robust approach for the preparation of functional nanomaterials.

Original language	English
Pages (from-to)	9782-9787
Number of pages	6
Journal	Chemical Science
Volume	10
Issue number	42
DOIs	https://doi.org/10.1039/c9sc03056e
State	Published - 2019
Externally published	Yes

Funding

This work is partially supported by the National Science Foundation EPSCoR Program under NSF Award # OIA-1655740.

Funders	Funder number
National Science Foundation EPSCoR Program
National Sleep Foundation	OIA-1655740

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10.1039/c9sc03056e

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abstract = "Polymerization-induced self-assembly (PISA) and crystallization-driven self-assembly (CDSA) are among the most prevailing methods for block copolymer self-assembly. Taking the merits of scalability of PISA and dimension control of CDSA, we report one-pot synchronous PISA and CDSA via ring-opening metathesis polymerization (ROMP) to prepare nano-objects based on a crystalline poly(ruthenocene) motif. We denote this self-assembly methodology as ROMPI-CDSA to enable a simple, yet robust approach for the preparation of functional nanomaterials.",

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T2 - Ring-opening metathesis polymerization-induced crystallization-driven self-assembly of metallo-block copolymers

AU - Sha, Ye

AU - Rahman, Md Anisur

AU - Zhu, Tianyu

AU - Cha, Yujin

AU - McAlister, C. Wayne

AU - Tang, Chuanbing

PY - 2019

Y1 - 2019

N2 - Polymerization-induced self-assembly (PISA) and crystallization-driven self-assembly (CDSA) are among the most prevailing methods for block copolymer self-assembly. Taking the merits of scalability of PISA and dimension control of CDSA, we report one-pot synchronous PISA and CDSA via ring-opening metathesis polymerization (ROMP) to prepare nano-objects based on a crystalline poly(ruthenocene) motif. We denote this self-assembly methodology as ROMPI-CDSA to enable a simple, yet robust approach for the preparation of functional nanomaterials.

AB - Polymerization-induced self-assembly (PISA) and crystallization-driven self-assembly (CDSA) are among the most prevailing methods for block copolymer self-assembly. Taking the merits of scalability of PISA and dimension control of CDSA, we report one-pot synchronous PISA and CDSA via ring-opening metathesis polymerization (ROMP) to prepare nano-objects based on a crystalline poly(ruthenocene) motif. We denote this self-assembly methodology as ROMPI-CDSA to enable a simple, yet robust approach for the preparation of functional nanomaterials.

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JO - Chemical Science

JF - Chemical Science

IS - 42

ER -

ROMPI-CDSA: Ring-opening metathesis polymerization-induced crystallization-driven self-assembly of metallo-block copolymers

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