Revealing the Correlations between Growth Recipe and Microscopic Structure of Bi-alkali/Multi-alkali Photocathodes

  • S. W. Lee
  • , K. Attenkofer
  • , M. Demarteau
  • , J. Smedley
  • , I. Ben-Zvi
  • , T. Rao
  • , M. Ruiz-Oses
  • , X. Liang
  • , E. M. Muller
  • , H. Padmore
  • , T. Vecchione

Research output: Contribution to journalConference articlepeer-review

Abstract

For the development of high quantum efficiency photocathodes, the bi-alkali (K-Cs-Sb) photocathode growth process was studied through in-situ X-ray scattering measurements, including X-ray diffractometry (XRD) and X-ray reflectometry (XRR). Characterization during real-time growth revealed correlations between growth parameters and microscopic structural change of the photocathode. This paper presents preliminary results of an ongoing experiment to understand the growth mechanism. X-ray diffractometry enabled the observation of selective growth of specific crystalline orientation during the deposition and evaporation of an Sb layer. A phase transition of the Sb layer was also measured. X-ray reflectometry revealed surface roughness changes during the growth process and permitted layer thickness measurements while the K layer was evaporated on an ex-situ grown Sb layer, in addition to in-situ Sb layer growth.

Original languageEnglish
Pages (from-to)765-772
Number of pages8
JournalPhysics Procedia
Volume37
DOIs
StatePublished - 2012
Externally publishedYes
Event2nd International Conference on Technology and Instrumentation in Particle Physics, TIPP 2011 - Chicago, United States
Duration: Jun 9 2011Jun 14 2011

Funding

The submitted manuscript has been created by UChicago Argonne, LLC, Operator of Argonne National Laboratory (“Argonne”). Argonne, a U.S. Department of Energy Office of Science laboratory, is operated under Contract No. DE-AC02-06CH11357. The U.S. Government retains for itself, and others acting on its behalf, a paid-up nonexclusive, irrevocable worldwide license in said article to reproduce, prepare derivative works, distribute copies to the public, and perform publicly and display publicly, by or on behalf of the Government.

Keywords

  • Multi-alkali photocathode
  • X-ray diffractometry
  • X-ray reflectometry
  • thin film growth

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