Resonant raman scattering of vibrationally highly excited supersonic-jet-cooled SO2 molecules

Yu G. Vainer; N. V. Gruzdev; A. A. Puretzky; E. G. Sil'kis; V. D. Titov

doi:10.1007/BF00332272

Resonant raman scattering of vibrationally highly excited supersonic-jet-cooled SO₂ molecules

Yu G. Vainer, N. V. Gruzdev, A. A. Puretzky, E. G. Sil'kis, V. D. Titov

Research output: Contribution to journal › Article › peer-review

Abstract

The resonant Raman scattering spectra of vibrationally highly excited SO₂ molecules with the vibrational energy of ∼3.7×10⁴ cm^-1 exhibit relatively wide (∼50 cm^-1) structurized bands. This spectral width is attributed to the mixing of vibrational levels of the ground electronic state ¹A₁ due to a non-adiabatic interaction with the vibrational levels of the electronically excited state ¹B₁.

Original language	English
Pages (from-to)	131-137
Number of pages	7
Journal	Applied Physics B Photophysics and Laser Chemistry
Volume	49
Issue number	2
DOIs	https://doi.org/10.1007/BF00332272
State	Published - Aug 1989
Externally published	Yes

Keywords

33.20.Fb
33.50Hv
34.30.+h

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10.1007/BF00332272

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title = "Resonant raman scattering of vibrationally highly excited supersonic-jet-cooled SO2 molecules",

abstract = "The resonant Raman scattering spectra of vibrationally highly excited SO2 molecules with the vibrational energy of ∼3.7×104 cm-1 exhibit relatively wide (∼50 cm-1) structurized bands. This spectral width is attributed to the mixing of vibrational levels of the ground electronic state 1A1 due to a non-adiabatic interaction with the vibrational levels of the electronically excited state 1B1.",

keywords = "33.20.Fb, 33.50Hv, 34.30.+h",

author = "Vainer, {Yu G.} and Gruzdev, {N. V.} and Puretzky, {A. A.} and Sil'kis, {E. G.} and Titov, {V. D.}",

year = "1989",

month = aug,

doi = "10.1007/BF00332272",

language = "English",

volume = "49",

pages = "131--137",

journal = "Applied Physics B Photophysics and Laser Chemistry",

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AU - Vainer, Yu G.

AU - Gruzdev, N. V.

AU - Puretzky, A. A.

AU - Sil'kis, E. G.

AU - Titov, V. D.

PY - 1989/8

Y1 - 1989/8

N2 - The resonant Raman scattering spectra of vibrationally highly excited SO2 molecules with the vibrational energy of ∼3.7×104 cm-1 exhibit relatively wide (∼50 cm-1) structurized bands. This spectral width is attributed to the mixing of vibrational levels of the ground electronic state 1A1 due to a non-adiabatic interaction with the vibrational levels of the electronically excited state 1B1.

AB - The resonant Raman scattering spectra of vibrationally highly excited SO2 molecules with the vibrational energy of ∼3.7×104 cm-1 exhibit relatively wide (∼50 cm-1) structurized bands. This spectral width is attributed to the mixing of vibrational levels of the ground electronic state 1A1 due to a non-adiabatic interaction with the vibrational levels of the electronically excited state 1B1.

KW - 33.20.Fb

KW - 33.50Hv

KW - 34.30.+h

UR - http://www.scopus.com/inward/record.url?scp=0024715328&partnerID=8YFLogxK

U2 - 10.1007/BF00332272

DO - 10.1007/BF00332272

M3 - Article

AN - SCOPUS:0024715328

SN - 0721-7269

VL - 49

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JO - Applied Physics B Photophysics and Laser Chemistry

JF - Applied Physics B Photophysics and Laser Chemistry

IS - 2

ER -

Resonant raman scattering of vibrationally highly excited supersonic-jet-cooled SO₂ molecules

Abstract

Keywords

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