Resonance laser ionization spectroscopy of tellurium

T. Kieck, Y. Liu, D. W. Stracener, R. Li, J. Lassen, K. D.A. Wendt

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    Abstract

    Resonance ionization schemes for tellurium are investigated with a resonance ionization laser ion source and Ti:Sapphire lasers for fundamental research applications. We present the first three-step resonance ionization spectra of atomic Te. Several autoionizing Rydberg series converging to the first excited state of Te+ are observed and assigned to 5p3 (2Do 3/2) ns and nd configurations. Our results include confirmation and significant expansion of the Rydberg series previously reported as well as observation of three new series. From the series convergence limits the ionization potential of tellurium is revised to be 72,669.006(42)stat(20)sys cm−1.

    Original languageEnglish
    Article number105645
    JournalSpectrochimica Acta - Part B Atomic Spectroscopy
    Volume159
    DOIs
    StatePublished - Sep 2019

    Funding

    This material is based upon work supported by the U.S. Department of Energy, Office of Science, Office of Nuclear Physics and this research used resources of the Holifield Radioactive Ion Beam Facility of Oak Ridge National Laboratory , which was a DOE Office of Science User Facility . One of us (T.K.) acknowledges financial support from the DFG Research Unit FOR 2202 (ECHo) under the contract DU 1334/1-1, R. Li and J. Lassen acknowledge support through TRIUMF which receives federal funding via a contribution agreement with the National Research Council of Canada (NRC) and through a Natural Sciences and Engineering Research Council of Canada (NSERC) Discovery Grant ( SAP-IN-2017-00039 ). This manuscript has been authored by UT-Battelle, LLC under Contract No. DE-AC05-00OR22725 with the U.S. Department of Energy. The United States Government retains and the publisher, by accepting the article for publication, acknowledges that the United States Government retains a non-exclusive, paid-up, irrevocable, world-wide license to publish or reproduce the published form of this manuscript, or allow others to do so, for United States Government purposes. The Department of Energy will provide public access to these results of federally sponsored research in accordance with the DOE Public Access Plan ( http://energy.gov/downloads/doe-public-access-plan ).

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