Resonance laser ionization spectroscopy of tellurium

T. Kieck, Y. Liu, D. W. Stracener, R. Li, J. Lassen, K. D.A. Wendt

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Abstract

Resonance ionization schemes for tellurium are investigated with a resonance ionization laser ion source and Ti:Sapphire lasers for fundamental research applications. We present the first three-step resonance ionization spectra of atomic Te. Several autoionizing Rydberg series converging to the first excited state of Te+ are observed and assigned to 5p3 (2Do 3/2) ns and nd configurations. Our results include confirmation and significant expansion of the Rydberg series previously reported as well as observation of three new series. From the series convergence limits the ionization potential of tellurium is revised to be 72,669.006(42)stat(20)sys cm−1.

Original languageEnglish
Article number105645
JournalSpectrochimica Acta - Part B Atomic Spectroscopy
Volume159
DOIs
StatePublished - Sep 2019

Funding

This material is based upon work supported by the R. Li and J. Lassen acknowledge support through TRIUMF which receives federal funding via a contribution agreement with the U.S. Department of Energy, Office of Science, Office of Nuclear Physics and this research used resources of the Holifield Radioactive Ion Beam Facility of Oak Ridge National Laboratory , which was a DOE Office of Science User Facility . One of us (T.K.) acknowledges financial support from the DFG Research Unit FOR 2202 (ECHo) under the contract DU 1334/1-1, National Research Council of Canada (NRC) and through a Natural Sciences and Engineering Research Council of Canada (NSERC) Discovery Grant ( SAP-IN-2017-00039 ).

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