Reinvestigation of NH4[Co(H2O)6]PO 4 based on single-crystal data

Brahim El Bali; Rachid Essehli; Francesco Capitelli; Mohammed Lachkar

doi:10.1107/S1600536805007245

Reinvestigation of NH₄[Co(H₂O)₆]PO ₄ based on single-crystal data

Brahim El Bali
, Rachid Essehli
, Francesco Capitelli
, Mohammed Lachkar

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

The structure of the title compound, ammonium hexaaquacobalt(II) orthophosphate, known from powder data, has been refined based on single-crystal data. The compound crystallizes in the struvite [NH ₄Mg(H₂O)₆PO₄] structure type and is isotypic with the homologous nickel phase. The framework is built of NH ₄⁺, [Co(H₂O)₆]²⁺ and PO₄^3- ions stacked in two kinds of ribbons parallel to (010). Co^II atoms are well separated in the framework, with the shortest Co⋯Co distance being over 6 Å.

Original language	English
Pages (from-to)	i52-i54
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	61
Issue number	4
DOIs	https://doi.org/10.1107/S1600536805007245
State	Published - Apr 2005
Externally published	Yes

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@article{12e86d065f814ec98bcd65bec69ba879,

title = "Reinvestigation of NH4[Co(H2O)6]PO 4 based on single-crystal data",

abstract = "The structure of the title compound, ammonium hexaaquacobalt(II) orthophosphate, known from powder data, has been refined based on single-crystal data. The compound crystallizes in the struvite [NH 4Mg(H2O)6PO4] structure type and is isotypic with the homologous nickel phase. The framework is built of NH 4+, [Co(H2O)6]2+ and PO43- ions stacked in two kinds of ribbons parallel to (010). CoII atoms are well separated in the framework, with the shortest Co⋯Co distance being over 6 {\AA}.",

author = "\{El Bali\}, Brahim and Rachid Essehli and Francesco Capitelli and Mohammed Lachkar",

year = "2005",

month = apr,

doi = "10.1107/S1600536805007245",

language = "English",

volume = "61",

pages = "i52--i54",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "4",

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TY - JOUR

T1 - Reinvestigation of NH4[Co(H2O)6]PO 4 based on single-crystal data

AU - El Bali, Brahim

AU - Essehli, Rachid

AU - Capitelli, Francesco

AU - Lachkar, Mohammed

PY - 2005/4

Y1 - 2005/4

N2 - The structure of the title compound, ammonium hexaaquacobalt(II) orthophosphate, known from powder data, has been refined based on single-crystal data. The compound crystallizes in the struvite [NH 4Mg(H2O)6PO4] structure type and is isotypic with the homologous nickel phase. The framework is built of NH 4+, [Co(H2O)6]2+ and PO43- ions stacked in two kinds of ribbons parallel to (010). CoII atoms are well separated in the framework, with the shortest Co⋯Co distance being over 6 Å.

AB - The structure of the title compound, ammonium hexaaquacobalt(II) orthophosphate, known from powder data, has been refined based on single-crystal data. The compound crystallizes in the struvite [NH 4Mg(H2O)6PO4] structure type and is isotypic with the homologous nickel phase. The framework is built of NH 4+, [Co(H2O)6]2+ and PO43- ions stacked in two kinds of ribbons parallel to (010). CoII atoms are well separated in the framework, with the shortest Co⋯Co distance being over 6 Å.

UR - https://www.scopus.com/pages/publications/18544381510

U2 - 10.1107/S1600536805007245

DO - 10.1107/S1600536805007245

M3 - Article

AN - SCOPUS:18544381510

SN - 1600-5368

VL - 61

SP - i52-i54

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 4

ER -

Reinvestigation of NH₄[Co(H₂O)₆]PO ₄ based on single-crystal data

Abstract

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