Redox potentials of uranium in molten eutectic mixture of lithium, potassium, and cesium chlorides

D. S. Maltsev; V. A. Volkovich; B. D. Vasin

doi:10.1134/S0036029516080115

Redox potentials of uranium in molten eutectic mixture of lithium, potassium, and cesium chlorides

D. S. Maltsev, V. A. Volkovich, B. D. Vasin

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The behavior of uranium(III) and (IV) ions in the melts based on the eutectic mixture of lithium, potassium, and cesium chlorides has been studied using cyclic voltammetry in the range of 573–1073 K. The red-ox potentials of uranium have been determined and formal standard E_U(III)/U(IV)* red-ox potentials have been calculated.

Original language	English
Pages (from-to)	729-732
Number of pages	4
Journal	Russian Metallurgy (Metally)
Volume	2016
Issue number	8
DOIs	https://doi.org/10.1134/S0036029516080115
State	Published - Aug 1 2016
Externally published	Yes

Keywords

chloride melts
red-ox potential
uranium

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10.1134/S0036029516080115

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abstract = "The behavior of uranium(III) and (IV) ions in the melts based on the eutectic mixture of lithium, potassium, and cesium chlorides has been studied using cyclic voltammetry in the range of 573–1073 K. The red-ox potentials of uranium have been determined and formal standard EU(III)/U(IV)* red-ox potentials have been calculated.",

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AU - Maltsev, D. S.

AU - Volkovich, V. A.

AU - Vasin, B. D.

PY - 2016/8/1

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N2 - The behavior of uranium(III) and (IV) ions in the melts based on the eutectic mixture of lithium, potassium, and cesium chlorides has been studied using cyclic voltammetry in the range of 573–1073 K. The red-ox potentials of uranium have been determined and formal standard EU(III)/U(IV)* red-ox potentials have been calculated.

AB - The behavior of uranium(III) and (IV) ions in the melts based on the eutectic mixture of lithium, potassium, and cesium chlorides has been studied using cyclic voltammetry in the range of 573–1073 K. The red-ox potentials of uranium have been determined and formal standard EU(III)/U(IV)* red-ox potentials have been calculated.

KW - chloride melts

KW - red-ox potential

KW - uranium

UR - http://www.scopus.com/inward/record.url?scp=85002388933&partnerID=8YFLogxK

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DO - 10.1134/S0036029516080115

M3 - Article

AN - SCOPUS:85002388933

SN - 0036-0295

VL - 2016

SP - 729

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JO - Russian Metallurgy (Metally)

JF - Russian Metallurgy (Metally)

IS - 8

ER -

Redox potentials of uranium in molten eutectic mixture of lithium, potassium, and cesium chlorides

Abstract

Keywords

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