Recent advancements in neutron scattering techniques for quantifying the structure and dynamics of polymers

Zhiqiang Cao, Yunfei Wang, Xiaodan Gu

Research output: Contribution to journalReview articlepeer-review

Abstract

Neutron scattering techniques are powerful tools for characterizing the structure and dynamics of materials. They are particularly well-suited for studying polymer systems, which are typically rich in hydrogen. By combining neutron scattering with deuterium labeling, researchers can unravel complex structural features and dynamic behaviors within these systems. This review highlights recent advances in neutron scattering methods for probing the hierarchical structures and dynamics of polymeric materials, with a focus on developments over the past decade. We begin by discussing elastic techniques—such as small-angle neutron scattering (SANS)—used to examine polymer organization in both solution and solid states. Subsequently, we address the application of neutron reflectometry (NR) and grazing-incidence neutron scattering (GINS) techniques to the study of polymer thin-film structures. Next, we explore inelastic and quasi-elastic techniques, including inelastic neutron scattering (INS), quasi-elastic neutron scattering (QENS), and neutron spin echo (NSE), which provide insight into polymer dynamics across a broad range of time and length scales. Finally, we consider future directions for neutron scattering in soft matter research, emphasizing emerging methodologies and next-generation neutron sources that promise to further advance our understanding of these complex systems.

Original languageEnglish
Article number102041
JournalProgress in Polymer Science
Volume171
DOIs
StatePublished - Dec 2025
Externally publishedYes

Funding

Z.C., Y,W. and X.G. thanks financial support from the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under award number DE-SC0022050, and DE-SC0024432, the Office of Naval Research (ONR) under the contract number N00014–23–1-2063 for the financial support, the National Science Foundation (NSF) under award number DMR-2047689, CHE-2304969 and OIA-2229686.

Keywords

  • Inelastic neutron scattering
  • Neutron scattering
  • Neutron spin echo
  • Polymer dynamics
  • Polymer structure
  • Quasi-elastic neutron scattering
  • Small-angle neutron scattering

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