Real space mapping of Li-ion transport in amorphous Si anodes with nanometer resolution

Nina Balke; Stephen Jesse; Yoongu Kim; Leslie Adamczyk; Alexander Tselev; Ilia N. Ivanov; Nancy J. Dudney; Sergei V. Kalinin

doi:10.1021/nl101439x

Real space mapping of Li-ion transport in amorphous Si anodes with nanometer resolution

Nina Balke, Stephen Jesse, Yoongu Kim, Leslie Adamczyk, Alexander Tselev, Ilia N. Ivanov, Nancy J. Dudney, Sergei V. Kalinin

Research output: Contribution to journal › Article › peer-review

233 Scopus citations

Abstract

The electrical bias driven Li-ion motion in silicon anode materials in thin film battery heterostructures is investigated using electrochemical strain microscopy (ESM), which is a newly developed scanning probe microscopy based characterization method. ESM utilizes the intrinsic link between bias-controlled Li-ion concentration and molar volume of electrode materials, providing the capability for studies on the sub-20 nm scale, and allows the relationship between Li-ion flow and microstructure to be established. The evolution of Li-ion transport during the battery charging is directly observed.

Original language	English
Pages (from-to)	3420-3425
Number of pages	6
Journal	Nano Letters
Volume	10
Issue number	9
DOIs	https://doi.org/10.1021/nl101439x
State	Published - Sep 8 2010

Keywords

Li-ion battery
scanning probe microscopy
thin films

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10.1021/nl101439x

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title = "Real space mapping of Li-ion transport in amorphous Si anodes with nanometer resolution",

abstract = "The electrical bias driven Li-ion motion in silicon anode materials in thin film battery heterostructures is investigated using electrochemical strain microscopy (ESM), which is a newly developed scanning probe microscopy based characterization method. ESM utilizes the intrinsic link between bias-controlled Li-ion concentration and molar volume of electrode materials, providing the capability for studies on the sub-20 nm scale, and allows the relationship between Li-ion flow and microstructure to be established. The evolution of Li-ion transport during the battery charging is directly observed.",

keywords = "Li-ion battery, scanning probe microscopy, thin films",

author = "Nina Balke and Stephen Jesse and Yoongu Kim and Leslie Adamczyk and Alexander Tselev and Ivanov, \{Ilia N.\} and Dudney, \{Nancy J.\} and Kalinin, \{Sergei V.\}",

year = "2010",

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doi = "10.1021/nl101439x",

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T1 - Real space mapping of Li-ion transport in amorphous Si anodes with nanometer resolution

AU - Balke, Nina

AU - Jesse, Stephen

AU - Kim, Yoongu

AU - Adamczyk, Leslie

AU - Tselev, Alexander

AU - Ivanov, Ilia N.

AU - Dudney, Nancy J.

AU - Kalinin, Sergei V.

PY - 2010/9/8

Y1 - 2010/9/8

N2 - The electrical bias driven Li-ion motion in silicon anode materials in thin film battery heterostructures is investigated using electrochemical strain microscopy (ESM), which is a newly developed scanning probe microscopy based characterization method. ESM utilizes the intrinsic link between bias-controlled Li-ion concentration and molar volume of electrode materials, providing the capability for studies on the sub-20 nm scale, and allows the relationship between Li-ion flow and microstructure to be established. The evolution of Li-ion transport during the battery charging is directly observed.

AB - The electrical bias driven Li-ion motion in silicon anode materials in thin film battery heterostructures is investigated using electrochemical strain microscopy (ESM), which is a newly developed scanning probe microscopy based characterization method. ESM utilizes the intrinsic link between bias-controlled Li-ion concentration and molar volume of electrode materials, providing the capability for studies on the sub-20 nm scale, and allows the relationship between Li-ion flow and microstructure to be established. The evolution of Li-ion transport during the battery charging is directly observed.

KW - Li-ion battery

KW - scanning probe microscopy

KW - thin films

UR - https://www.scopus.com/pages/publications/77956438518

U2 - 10.1021/nl101439x

DO - 10.1021/nl101439x

M3 - Article

AN - SCOPUS:77956438518

SN - 1530-6984

VL - 10

SP - 3420

EP - 3425

JO - Nano Letters

JF - Nano Letters

IS - 9

ER -

Real space mapping of Li-ion transport in amorphous Si anodes with nanometer resolution

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Keywords

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