Reaction of uranium(IV) chloride with oxygen in alkali chloride melts: An electronic absorption spectroscopy study

A. A. Kozlova; A. A. Ryzhov; A. B. Ivanov; D. S. Maltsev; A. V. Shchetinskiy; A. V. Novoselova; V. A. Volkovich

doi:10.1063/1.5134185

Reaction of uranium(IV) chloride with oxygen in alkali chloride melts: An electronic absorption spectroscopy study

A. A. Kozlova, A. A. Ryzhov, A. B. Ivanov, D. S. Maltsev, A. V. Shchetinskiy, A. V. Novoselova, V. A. Volkovich

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

2 Scopus citations

Abstract

Electronic absorption spectroscopy was applied for studying the reaction of uranium(IV) chloride with oxygen in alkali chloride based melts. The experiments were performed at 450-750 °C in the melts based on LiCl-KCl, NaCl- CsCl and NaCl-KCl-CsCl eutectic mixtures. Effect of diluting oxygen with an inert gas and presence of water vapor on the oxidation reaction was also considered.

Original language	English
Title of host publication	Physics, Technologies and Innovation, PTI 2019
Subtitle of host publication	Proceedings of the VI International Young Researchers� Conference
Editors	Vladimir A. Volkovich, Sergey V. Zvonarev, Ilya V. Kashin, Andrey A. Smirnov, Evgeniy D. Narkhov
Publisher	American Institute of Physics Inc.
ISBN (Electronic)	9780735419216
DOIs	https://doi.org/10.1063/1.5134185
State	Published - Dec 6 2019
Externally published	Yes
Event	6th International Young Researchers'' Conference on Physics, Technologies and Innovation, PTI 2019 - Ekaterinburg, Russian Federation Duration: May 20 2019 → May 23 2019

Publication series

Name	AIP Conference Proceedings
Volume	2174
ISSN (Print)	0094-243X
ISSN (Electronic)	1551-7616

Conference

Conference	6th International Young Researchers'' Conference on Physics, Technologies and Innovation, PTI 2019
Country/Territory	Russian Federation
City	Ekaterinburg
Period	05/20/19 → 05/23/19

Funding

The present study was supported by RFBR according to the research project No. 17-03-00694.

Access to Document

10.1063/1.5134185

Cite this

Kozlova, A. A., Ryzhov, A. A., Ivanov, A. B., Maltsev, D. S., Shchetinskiy, A. V., Novoselova, A. V., & Volkovich, V. A. (2019). Reaction of uranium(IV) chloride with oxygen in alkali chloride melts: An electronic absorption spectroscopy study. In V. A. Volkovich, S. V. Zvonarev, I. V. Kashin, A. A. Smirnov, & E. D. Narkhov (Eds.), Physics, Technologies and Innovation, PTI 2019: Proceedings of the VI International Young Researchers� Conference Article 020034 (AIP Conference Proceedings; Vol. 2174). American Institute of Physics Inc.. https://doi.org/10.1063/1.5134185

Kozlova, A. A. ; Ryzhov, A. A. ; Ivanov, A. B. et al. / Reaction of uranium(IV) chloride with oxygen in alkali chloride melts : An electronic absorption spectroscopy study. Physics, Technologies and Innovation, PTI 2019: Proceedings of the VI International Young Researchers� Conference. editor / Vladimir A. Volkovich ; Sergey V. Zvonarev ; Ilya V. Kashin ; Andrey A. Smirnov ; Evgeniy D. Narkhov. American Institute of Physics Inc., 2019. (AIP Conference Proceedings).

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title = "Reaction of uranium(IV) chloride with oxygen in alkali chloride melts: An electronic absorption spectroscopy study",

abstract = "Electronic absorption spectroscopy was applied for studying the reaction of uranium(IV) chloride with oxygen in alkali chloride based melts. The experiments were performed at 450-750 °C in the melts based on LiCl-KCl, NaCl- CsCl and NaCl-KCl-CsCl eutectic mixtures. Effect of diluting oxygen with an inert gas and presence of water vapor on the oxidation reaction was also considered.",

author = "Kozlova, \{A. A.\} and Ryzhov, \{A. A.\} and Ivanov, \{A. B.\} and Maltsev, \{D. S.\} and Shchetinskiy, \{A. V.\} and Novoselova, \{A. V.\} and Volkovich, \{V. A.\}",

note = "Publisher Copyright: {\textcopyright} 2019 Author(s).; 6th International Young Researchers'' Conference on Physics, Technologies and Innovation, PTI 2019 ; Conference date: 20-05-2019 Through 23-05-2019",

year = "2019",

month = dec,

day = "6",

doi = "10.1063/1.5134185",

language = "English",

series = "AIP Conference Proceedings",

publisher = "American Institute of Physics Inc.",

editor = "Volkovich, \{Vladimir A.\} and Zvonarev, \{Sergey V.\} and Kashin, \{Ilya V.\} and Smirnov, \{Andrey A.\} and Narkhov, \{Evgeniy D.\}",

booktitle = "Physics, Technologies and Innovation, PTI 2019",

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Kozlova, AA, Ryzhov, AA, Ivanov, AB, Maltsev, DS, Shchetinskiy, AV, Novoselova, AV & Volkovich, VA 2019, Reaction of uranium(IV) chloride with oxygen in alkali chloride melts: An electronic absorption spectroscopy study. in VA Volkovich, SV Zvonarev, IV Kashin, AA Smirnov & ED Narkhov (eds), Physics, Technologies and Innovation, PTI 2019: Proceedings of the VI International Young Researchers� Conference., 020034, AIP Conference Proceedings, vol. 2174, American Institute of Physics Inc., 6th International Young Researchers'' Conference on Physics, Technologies and Innovation, PTI 2019, Ekaterinburg, Russian Federation, 05/20/19. https://doi.org/10.1063/1.5134185

Reaction of uranium(IV) chloride with oxygen in alkali chloride melts: An electronic absorption spectroscopy study. / Kozlova, A. A.; Ryzhov, A. A.; Ivanov, A. B. et al.
Physics, Technologies and Innovation, PTI 2019: Proceedings of the VI International Young Researchers� Conference. ed. / Vladimir A. Volkovich; Sergey V. Zvonarev; Ilya V. Kashin; Andrey A. Smirnov; Evgeniy D. Narkhov. American Institute of Physics Inc., 2019. 020034 (AIP Conference Proceedings; Vol. 2174).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

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T2 - 6th International Young Researchers'' Conference on Physics, Technologies and Innovation, PTI 2019

AU - Kozlova, A. A.

AU - Ryzhov, A. A.

AU - Ivanov, A. B.

AU - Maltsev, D. S.

AU - Shchetinskiy, A. V.

AU - Novoselova, A. V.

AU - Volkovich, V. A.

PY - 2019/12/6

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N2 - Electronic absorption spectroscopy was applied for studying the reaction of uranium(IV) chloride with oxygen in alkali chloride based melts. The experiments were performed at 450-750 °C in the melts based on LiCl-KCl, NaCl- CsCl and NaCl-KCl-CsCl eutectic mixtures. Effect of diluting oxygen with an inert gas and presence of water vapor on the oxidation reaction was also considered.

AB - Electronic absorption spectroscopy was applied for studying the reaction of uranium(IV) chloride with oxygen in alkali chloride based melts. The experiments were performed at 450-750 °C in the melts based on LiCl-KCl, NaCl- CsCl and NaCl-KCl-CsCl eutectic mixtures. Effect of diluting oxygen with an inert gas and presence of water vapor on the oxidation reaction was also considered.

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DO - 10.1063/1.5134185

M3 - Conference contribution

AN - SCOPUS:85076591040

T3 - AIP Conference Proceedings

BT - Physics, Technologies and Innovation, PTI 2019

A2 - Volkovich, Vladimir A.

A2 - Zvonarev, Sergey V.

A2 - Kashin, Ilya V.

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PB - American Institute of Physics Inc.

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ER -

Kozlova AA, Ryzhov AA, Ivanov AB, Maltsev DS, Shchetinskiy AV, Novoselova AV et al. Reaction of uranium(IV) chloride with oxygen in alkali chloride melts: An electronic absorption spectroscopy study. In Volkovich VA, Zvonarev SV, Kashin IV, Smirnov AA, Narkhov ED, editors, Physics, Technologies and Innovation, PTI 2019: Proceedings of the VI International Young Researchers� Conference. American Institute of Physics Inc. 2019. 020034. (AIP Conference Proceedings). doi: 10.1063/1.5134185

Reaction of uranium(IV) chloride with oxygen in alkali chloride melts: An electronic absorption spectroscopy study

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