Rapid activation product separations from fission products and soil matrixes

Kevin T. Bennett; Stosh A. Kozimor; Benjamin T. Manard; Veronika Mocko; Susan D. Pacheco; Ann R. Schake; Ruilian Wu; Angela C. Olson

doi:10.1007/s10967-019-06678-4

Rapid activation product separations from fission products and soil matrixes

Kevin T. Bennett, Stosh A. Kozimor, Benjamin T. Manard, Veronika Mocko, Susan D. Pacheco, Ann R. Schake, Ruilian Wu, Angela C. Olson

Chemical & Isotopic Mass Spectrometry

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

A rapid method for the separation and qualitative analysis of several neutron activation products (¹⁹⁸Au, ¹⁹²Ir, ⁷²Ga, ⁵¹Cr, ^191/195m/197Pt, ⁵⁴Mn, ⁵⁷Co, and ⁵⁹Fe) from fission products and soil matrixes has been developed. Analytes were isolated within 20 h using ion exchange chromatography. After separation, the activation products were characterized by γ-spectroscopy and inductively coupled plasma-optical emission spectroscopy. Validation experiments demonstrated versatility of the method, showing that the activation products could be isolated from fresh fission products and other contaminants associated with complex soil matrixes.

Original language	English
Pages (from-to)	281-289
Number of pages	9
Journal	Journal of Radioanalytical and Nuclear Chemistry
Volume	322
Issue number	2
DOIs	https://doi.org/10.1007/s10967-019-06678-4
State	Published - Nov 1 2019

Funding

The authors are grateful for support from the Defense Threat Reduction Agency.

Keywords

Activation products
Fission products
ICP-OES
Rapid separation

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10.1007/s10967-019-06678-4

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title = "Rapid activation product separations from fission products and soil matrixes",

abstract = "A rapid method for the separation and qualitative analysis of several neutron activation products (198Au, 192Ir, 72Ga, 51Cr, 191/195m/197Pt, 54Mn, 57Co, and 59Fe) from fission products and soil matrixes has been developed. Analytes were isolated within 20 h using ion exchange chromatography. After separation, the activation products were characterized by γ-spectroscopy and inductively coupled plasma-optical emission spectroscopy. Validation experiments demonstrated versatility of the method, showing that the activation products could be isolated from fresh fission products and other contaminants associated with complex soil matrixes.",

keywords = "Activation products, Fission products, ICP-OES, Rapid separation",

author = "Bennett, \{Kevin T.\} and Kozimor, \{Stosh A.\} and Manard, \{Benjamin T.\} and Veronika Mocko and Pacheco, \{Susan D.\} and Schake, \{Ann R.\} and Ruilian Wu and Olson, \{Angela C.\}",

note = "Publisher Copyright: {\textcopyright} 2019, This is a U.S. Government work and not under copyright protection in the US; foreign copyright protection may apply.",

year = "2019",

month = nov,

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doi = "10.1007/s10967-019-06678-4",

language = "English",

volume = "322",

pages = "281--289",

journal = "Journal of Radioanalytical and Nuclear Chemistry",

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T1 - Rapid activation product separations from fission products and soil matrixes

AU - Bennett, Kevin T.

AU - Kozimor, Stosh A.

AU - Manard, Benjamin T.

AU - Mocko, Veronika

AU - Pacheco, Susan D.

AU - Schake, Ann R.

AU - Wu, Ruilian

AU - Olson, Angela C.

PY - 2019/11/1

Y1 - 2019/11/1

N2 - A rapid method for the separation and qualitative analysis of several neutron activation products (198Au, 192Ir, 72Ga, 51Cr, 191/195m/197Pt, 54Mn, 57Co, and 59Fe) from fission products and soil matrixes has been developed. Analytes were isolated within 20 h using ion exchange chromatography. After separation, the activation products were characterized by γ-spectroscopy and inductively coupled plasma-optical emission spectroscopy. Validation experiments demonstrated versatility of the method, showing that the activation products could be isolated from fresh fission products and other contaminants associated with complex soil matrixes.

AB - A rapid method for the separation and qualitative analysis of several neutron activation products (198Au, 192Ir, 72Ga, 51Cr, 191/195m/197Pt, 54Mn, 57Co, and 59Fe) from fission products and soil matrixes has been developed. Analytes were isolated within 20 h using ion exchange chromatography. After separation, the activation products were characterized by γ-spectroscopy and inductively coupled plasma-optical emission spectroscopy. Validation experiments demonstrated versatility of the method, showing that the activation products could be isolated from fresh fission products and other contaminants associated with complex soil matrixes.

KW - Activation products

KW - Fission products

KW - ICP-OES

KW - Rapid separation

UR - https://www.scopus.com/pages/publications/85070230305

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DO - 10.1007/s10967-019-06678-4

M3 - Article

AN - SCOPUS:85070230305

SN - 0236-5731

VL - 322

SP - 281

EP - 289

JO - Journal of Radioanalytical and Nuclear Chemistry

JF - Journal of Radioanalytical and Nuclear Chemistry

IS - 2

ER -

Rapid activation product separations from fission products and soil matrixes

Abstract

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