Pyrolysis of soybean soapstock for hydrocarbon bio-oil over a microwave-responsive catalyst in a series microwave system

Qiuhao Wu; Lin Jiang; Yunpu Wang; Leilei Dai; Yuhuan Liu; Rongge Zou; Xiaojie Tian; Linyao Ke; Xiuhua Yang; Roger Ruan

doi:10.1016/j.biortech.2021.125800

Pyrolysis of soybean soapstock for hydrocarbon bio-oil over a microwave-responsive catalyst in a series microwave system

Qiuhao Wu, Lin Jiang, Yunpu Wang, Leilei Dai, Yuhuan Liu, Rongge Zou, Xiaojie Tian, Linyao Ke, Xiuhua Yang, Roger Ruan

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

A novel Silicon carbide (SiC) foam ceramic based ZSM-5/SiC nanowires microwave-responsive catalyst was developed to upgrade the pyrolysis volatiles in a microwave-assisted series system (both the pyrolysis and catalytic systems were heated by microwave). The growth of SiC nanowires was helpful for the ZSM-5 growth on the SiC foam ceramic. Because the specific surface area of SiC foam ceramic was improved. The dielectric properties of the composite catalyst were improved due to the growth of SiC nanowires. Bio-oil composition analysis showed that area percentage of hydrocarbons and aromatic hydrocarbons could reach 80.89% and 40.48% at catalytic temperature of 450 ℃and 500 ℃, respectively. The microwave-responsive composite catalyst had good aromatization performance in microwave-assisted series system due to high dielectric properties and specific surface area. The composite catalyst performed well after five-cycle regeneration, and the hydrocarbon content could still reach 76.40%, which is 80.89% for the original catalyst.

Original language	English
Article number	125800
Journal	Bioresource Technology
Volume	341
DOIs	https://doi.org/10.1016/j.biortech.2021.125800
State	Published - Dec 2021
Externally published	Yes

Funding

This project was financially supported by the National Natural Science Foundation of China (No. 21766019 ; No. 21878137 ), The Centrally Guided Local Science Technology Special Project ( 20202ZDB01012 ), The Major Discipline Academic and Technical Leaders Training Program of Jiangxi Province ( 20204BCJ23011 ), Graduate Student Innovation Project of Jiangxi Province ( YC2020-S005 ).

Funders	Funder number
Centrally Guided Local Science Technology Special Project	20202ZDB01012
Graduate Student Innovation Project of Jiangxi Province	YC2020-S005
National Natural Science Foundation of China	21878137, 21766019
National Natural Science Foundation of China
Major Discipline Academic and Technical Leaders Training Program of Jiangxi Province	20204BCJ23011
Major Discipline Academic and Technical Leaders Training Program of Jiangxi Province

Keywords

Hydrocarbons
Microwave-responsive catalysis
Pyrolysis
Soybean soapstock
ZSM-5

Access to Document

10.1016/j.biortech.2021.125800

Cite this

@article{4b0e0ad623cb4199b5cba2f165add5ab,

title = "Pyrolysis of soybean soapstock for hydrocarbon bio-oil over a microwave-responsive catalyst in a series microwave system",

abstract = "A novel Silicon carbide (SiC) foam ceramic based ZSM-5/SiC nanowires microwave-responsive catalyst was developed to upgrade the pyrolysis volatiles in a microwave-assisted series system (both the pyrolysis and catalytic systems were heated by microwave). The growth of SiC nanowires was helpful for the ZSM-5 growth on the SiC foam ceramic. Because the specific surface area of SiC foam ceramic was improved. The dielectric properties of the composite catalyst were improved due to the growth of SiC nanowires. Bio-oil composition analysis showed that area percentage of hydrocarbons and aromatic hydrocarbons could reach 80.89% and 40.48% at catalytic temperature of 450 ℃and 500 ℃, respectively. The microwave-responsive composite catalyst had good aromatization performance in microwave-assisted series system due to high dielectric properties and specific surface area. The composite catalyst performed well after five-cycle regeneration, and the hydrocarbon content could still reach 76.40%, which is 80.89% for the original catalyst.",

keywords = "Hydrocarbons, Microwave-responsive catalysis, Pyrolysis, Soybean soapstock, ZSM-5",

author = "Qiuhao Wu and Lin Jiang and Yunpu Wang and Leilei Dai and Yuhuan Liu and Rongge Zou and Xiaojie Tian and Linyao Ke and Xiuhua Yang and Roger Ruan",

note = "Publisher Copyright: {\textcopyright} 2021 Elsevier Ltd",

year = "2021",

month = dec,

doi = "10.1016/j.biortech.2021.125800",

language = "English",

volume = "341",

journal = "Bioresource Technology",

issn = "0960-8524",

publisher = "Elsevier",

}

TY - JOUR

T1 - Pyrolysis of soybean soapstock for hydrocarbon bio-oil over a microwave-responsive catalyst in a series microwave system

AU - Wu, Qiuhao

AU - Jiang, Lin

AU - Wang, Yunpu

AU - Dai, Leilei

AU - Liu, Yuhuan

AU - Zou, Rongge

AU - Tian, Xiaojie

AU - Ke, Linyao

AU - Yang, Xiuhua

AU - Ruan, Roger

PY - 2021/12

Y1 - 2021/12

N2 - A novel Silicon carbide (SiC) foam ceramic based ZSM-5/SiC nanowires microwave-responsive catalyst was developed to upgrade the pyrolysis volatiles in a microwave-assisted series system (both the pyrolysis and catalytic systems were heated by microwave). The growth of SiC nanowires was helpful for the ZSM-5 growth on the SiC foam ceramic. Because the specific surface area of SiC foam ceramic was improved. The dielectric properties of the composite catalyst were improved due to the growth of SiC nanowires. Bio-oil composition analysis showed that area percentage of hydrocarbons and aromatic hydrocarbons could reach 80.89% and 40.48% at catalytic temperature of 450 ℃and 500 ℃, respectively. The microwave-responsive composite catalyst had good aromatization performance in microwave-assisted series system due to high dielectric properties and specific surface area. The composite catalyst performed well after five-cycle regeneration, and the hydrocarbon content could still reach 76.40%, which is 80.89% for the original catalyst.

AB - A novel Silicon carbide (SiC) foam ceramic based ZSM-5/SiC nanowires microwave-responsive catalyst was developed to upgrade the pyrolysis volatiles in a microwave-assisted series system (both the pyrolysis and catalytic systems were heated by microwave). The growth of SiC nanowires was helpful for the ZSM-5 growth on the SiC foam ceramic. Because the specific surface area of SiC foam ceramic was improved. The dielectric properties of the composite catalyst were improved due to the growth of SiC nanowires. Bio-oil composition analysis showed that area percentage of hydrocarbons and aromatic hydrocarbons could reach 80.89% and 40.48% at catalytic temperature of 450 ℃and 500 ℃, respectively. The microwave-responsive composite catalyst had good aromatization performance in microwave-assisted series system due to high dielectric properties and specific surface area. The composite catalyst performed well after five-cycle regeneration, and the hydrocarbon content could still reach 76.40%, which is 80.89% for the original catalyst.

KW - Hydrocarbons

KW - Microwave-responsive catalysis

KW - Pyrolysis

KW - Soybean soapstock

KW - ZSM-5

UR - http://www.scopus.com/inward/record.url?scp=85113296540&partnerID=8YFLogxK

U2 - 10.1016/j.biortech.2021.125800

DO - 10.1016/j.biortech.2021.125800

M3 - Article

C2 - 34438288

AN - SCOPUS:85113296540

SN - 0960-8524

VL - 341

JO - Bioresource Technology

JF - Bioresource Technology

M1 - 125800

ER -

Pyrolysis of soybean soapstock for hydrocarbon bio-oil over a microwave-responsive catalyst in a series microwave system

Abstract

Funding

Keywords

Access to Document

Other files and links

Fingerprint

Cite this