Pulse radiolysis of concentrated sulfuric acid

P. S. Polevoi; A. E. Khachaturov-Tavrizian; I. N. Ivanov

doi:10.1016/1359-0197(90)90221-3

Pulse radiolysis of concentrated sulfuric acid

P. S. Polevoi
, A. E. Khachaturov-Tavrizian
, I. N. Ivanov

Research output: Contribution to journal › Conference article › peer-review

5 Scopus citations

Abstract

The pulse radiolysis method is used to study the optical absorption spectra in azeotropic sulfuric acid at 298 and 373 K. The spectra showing maximum absorption at 460 and 275 nm, observed at 298 K in the acid saturated with N₂, are associated with the radicals of HSO₄ and HSO₃, respectively. An additional absorption band of HSO₅ radical having a maximum at 245 nm appears in the acid saturated with O₂ at 298 K and in the acid saturated with N₂ at 373 K. It is suggested that the short-lived (under 1 μs) absorption bands with the maximums at ca 380 and 290 nm belong to the transient species H₂SO₄^- and H₂SO₄⁺, respectively. The obtained results are used to construct the machanism of the early stages of the low- and high-temperature radiolysis of concentrated sulfuric acid.

Original language	English
Pages (from-to)	99-103
Number of pages	5
Journal	Radiation Physics and Chemistry
Volume	36
Issue number	2
DOIs	https://doi.org/10.1016/1359-0197(90)90221-3
State	Published - 1990
Externally published	Yes
Event	Second International Meeting on Pulse Investigations in Physics, Chemistry and Biology - Czerniejewo, Pol Duration: Sep 12 1988 → Sep 17 1988

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10.1016/1359-0197(90)90221-3

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@article{e7553e2609a54a36b3e11dbee7c2fd67,

title = "Pulse radiolysis of concentrated sulfuric acid",

abstract = "The pulse radiolysis method is used to study the optical absorption spectra in azeotropic sulfuric acid at 298 and 373 K. The spectra showing maximum absorption at 460 and 275 nm, observed at 298 K in the acid saturated with N2, are associated with the radicals of HSO4 and HSO3, respectively. An additional absorption band of HSO5 radical having a maximum at 245 nm appears in the acid saturated with O2 at 298 K and in the acid saturated with N2 at 373 K. It is suggested that the short-lived (under 1 μs) absorption bands with the maximums at ca 380 and 290 nm belong to the transient species H2SO4- and H2SO4+, respectively. The obtained results are used to construct the machanism of the early stages of the low- and high-temperature radiolysis of concentrated sulfuric acid.",

author = "Polevoi, \{P. S.\} and Khachaturov-Tavrizian, \{A. E.\} and Ivanov, \{I. N.\}",

year = "1990",

doi = "10.1016/1359-0197(90)90221-3",

language = "English",

volume = "36",

pages = "99--103",

journal = "Radiation Physics and Chemistry",

issn = "0146-5724",

publisher = "Elsevier",

number = "2",

note = "Second International Meeting on Pulse Investigations in Physics, Chemistry and Biology ; Conference date: 12-09-1988 Through 17-09-1988",

}

TY - JOUR

T1 - Pulse radiolysis of concentrated sulfuric acid

AU - Polevoi, P. S.

AU - Khachaturov-Tavrizian, A. E.

AU - Ivanov, I. N.

PY - 1990

Y1 - 1990

N2 - The pulse radiolysis method is used to study the optical absorption spectra in azeotropic sulfuric acid at 298 and 373 K. The spectra showing maximum absorption at 460 and 275 nm, observed at 298 K in the acid saturated with N2, are associated with the radicals of HSO4 and HSO3, respectively. An additional absorption band of HSO5 radical having a maximum at 245 nm appears in the acid saturated with O2 at 298 K and in the acid saturated with N2 at 373 K. It is suggested that the short-lived (under 1 μs) absorption bands with the maximums at ca 380 and 290 nm belong to the transient species H2SO4- and H2SO4+, respectively. The obtained results are used to construct the machanism of the early stages of the low- and high-temperature radiolysis of concentrated sulfuric acid.

AB - The pulse radiolysis method is used to study the optical absorption spectra in azeotropic sulfuric acid at 298 and 373 K. The spectra showing maximum absorption at 460 and 275 nm, observed at 298 K in the acid saturated with N2, are associated with the radicals of HSO4 and HSO3, respectively. An additional absorption band of HSO5 radical having a maximum at 245 nm appears in the acid saturated with O2 at 298 K and in the acid saturated with N2 at 373 K. It is suggested that the short-lived (under 1 μs) absorption bands with the maximums at ca 380 and 290 nm belong to the transient species H2SO4- and H2SO4+, respectively. The obtained results are used to construct the machanism of the early stages of the low- and high-temperature radiolysis of concentrated sulfuric acid.

UR - https://www.scopus.com/pages/publications/0025307763

U2 - 10.1016/1359-0197(90)90221-3

DO - 10.1016/1359-0197(90)90221-3

M3 - Conference article

AN - SCOPUS:0025307763

SN - 0146-5724

VL - 36

SP - 99

EP - 103

JO - Radiation Physics and Chemistry

JF - Radiation Physics and Chemistry

IS - 2

T2 - Second International Meeting on Pulse Investigations in Physics, Chemistry and Biology

Y2 - 12 September 1988 through 17 September 1988

ER -

Pulse radiolysis of concentrated sulfuric acid

Abstract

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