Abstract
Gas nitridation has shown excellent promise to form dense, electrically conductive and corrosion-resistant Cr-nitride surface layers on Ni-Cr base alloys for use as proton exchange membrane fuel cell (PEMFC) bipolar plates. Due to the high cost of nickel, Fe-base bipolar plate alloys are needed to meet the cost targets for many PEMFC applications. Unfortunately, nitridation of Fe-base stainless steel alloys typically leads to internal Cr-nitride precipitation rather than the desired protective surface nitride layer formation, due to the high permeability of nitrogen in these alloys. This paper reports the finding that it is possible to form a continuous, protective Cr-nitride (CrN and Cr2N) surface layer through nitridation of Fe-base stainless steel alloys. The key to form a protective Cr-nitride surface layer was found to be the initial formation of oxide during nitridation, which prevented the internal nitridation typically observed for these alloys, and resulted in external Cr-nitride layer formation. The addition of V to the alloy, which resulted in the initial formation of V2O3-Cr2O3, was found to enhance this effect, by making the initially formed oxide more amenable to subsequent nitridation. The Cr-nitride surface layer formed on model V-modified Fe-27Cr alloys exhibited excellent corrosion resistance and low interfacial contact resistance under simulated PEMFC bipolar plate conditions.
Original language | English |
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Pages (from-to) | 228-236 |
Number of pages | 9 |
Journal | Journal of Power Sources |
Volume | 174 |
Issue number | 1 |
DOIs | |
State | Published - Nov 22 2007 |
Funding
This work was funded by the United States Department of Energy (USDOE) Hydrogen, Fuel Cells, and Infrastructure program. Oak Ridge National Laboratory is managed by UT-Battelle, LLC for the USDOE under contract DE-AC05-00OR22725. The authors thank D.F. Wilson, Y. Yamamoto, and Joachim Schneibel for comments on this manuscript, G. Teeter for conducting the AES measurements, and J.M. Vitek and C.E. Duty for input regarding solubility and diffusivity data for the Wagner criteria calculations. The Oak Ridge National Laboratory (ORNL) SHaRE Collaborative Research Center is also gratefully acknowledged.
Keywords
- Corrosion
- Electrical properties
- Nitridation
- Nitrides
- Oxidation
- Stainless steels