Production of AlN/CNT reinforced PVA nanofibers as a thermal conductive net for thermal interface applications

Suna Avcıoğlu, Mücahid Özcan, Cengiz Kaya, Figen Kaya, Sinem Çevik

Research output: Contribution to journalArticlepeer-review

1 Scopus citations

Abstract

The amount of heat generated by electronic components is increasing daily, in line with their growing power and performance. Consequently, there is a heightened demand for thermal interface materials for enhanced cooling of electronics. This study employs a novel approach to fabricate a nano composite thermal interface material on copper substrates to address this challenge. The thermal interface coatings, consisting of carbon nanotubes (CNT) and aluminum nitride (AlN)-reinforced polyvinyl alcohol (PVA) nanofibers with and without an epoxy resin matrix, are fabricated using the electrospinning technique. The findings demonstrate the successful fabrication of a 2.5 µm-thick CNT/AlN-PVA nanocomposite fiber mat coating with an average fiber diameter of 318 nm onto copper substrates. Scanning electron microscope (SEM) images revealed that the AlN particles and CNTs penetrated the fibers. The successful incorporation of AlN particles into PVA fibers was also verified by the Fourier-transform infrared spectroscopy (FT-IR) spectrum of CNT/AlN-PVA nanofibers. No major weight loss was observed in the thermogravimetric (TG) analysis curves up to 200 °C, indicating the thermal stability of coatings. The thermal diffusivity of the copper substrate coated with the CNT/AlN-PVA nanocomposite fiber mat was measured at 36.6 mm2/s. Moreover, the developed CNT/AlN-PVA nanocomposite fiber mat was also applied on top of the fire-retardant epoxy resin-coated copper substrate, which is conventionally used in electronic devices to provide electrical insulation. SEM images revealed that the existence of an epoxy layer on top of copper substrates did not alter the fiber formation during the electrospinning process, and an approximately 2.5 µm-thick CNT/AlN-PVA nanofiber mat was effectively embedded in the epoxy layer after a 1-hour electrospinning process. The thermal diffusivity of the resulting epoxy matrix CNT/AlN-PVA nanofiber reinforced nanocomposite coating is determined to be 7.792 mm2/s, which is 30-fold higher compared to the thermal diffusivity of neat epoxy resin coatings (0.254 mm2/s).

Original languageEnglish
Article number112404
JournalInorganic Chemistry Communications
Volume164
DOIs
StatePublished - Jun 2024
Externally publishedYes

Funding

The authors are grateful for the financial support from the Ondokuz May\u0131s University under the contract number of PYO.MUH.1901.18.006.

Keywords

  • Aluminum nitride
  • Carbon nanotube
  • Epoxy resin
  • Thermal conductivity

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