Abstract
We report that the pressure coefficient of the glass transition temperature, dT g/dp, which is commonly used to determine the pressure sensitivity of the glass transition temperature T g, can be predicted in the thermodynamic scaling regime. We show that the equation derived from the isochronal condition combined with the well-known scaling, TVγ = const, predicts successfully values of dT g/dp for a variety of glass-forming systems, including van der Waals liquids, polymers, and ionic liquids.
| Original language | English |
|---|---|
| Article number | 041502 |
| Journal | Physical Review E - Statistical, Nonlinear, and Soft Matter Physics |
| Volume | 86 |
| Issue number | 4 |
| DOIs | |
| State | Published - Oct 8 2012 |
| Externally published | Yes |
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