Polyureas derived from CO2 and diamines: highly efficient catalysts for C-H arylation of benzene

Zhenghui Liu; Zhenzhen Yang; Leiduan Hao; Xinwei Liu; Hongye Zhang; Bo Yu; Zhimin Liu

doi:10.1039/c6nj02785g

Polyureas derived from CO₂ and diamines: highly efficient catalysts for C-H arylation of benzene

Zhenghui Liu, Zhenzhen Yang, Leiduan Hao, Xinwei Liu, Hongye Zhang, Bo Yu, Zhimin Liu

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10 Scopus citations

Abstract

Polyureas derived from CO₂ and diamines were effective for C-H arylation of benzene in the presence of t-BuOK, producing biaryl products with various substituents in high yields up to 97%. Dual-activation of K⁺ and t-BuO^-, and π,π-stacking interaction between the substrate and the polymer backbone may account for the superior activity.

Original language	English
Pages (from-to)	51-55
Number of pages	5
Journal	New Journal of Chemistry
Volume	41
Issue number	1
DOIs	https://doi.org/10.1039/c6nj02785g
State	Published - 2016
Externally published	Yes

Funding

This work was financially supported by the National Natural Science Foundation of China (grant no. 21402208, 21533011, and 21125314).

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10.1039/c6nj02785g

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title = "Polyureas derived from CO2 and diamines: highly efficient catalysts for C-H arylation of benzene",

abstract = "Polyureas derived from CO2 and diamines were effective for C-H arylation of benzene in the presence of t-BuOK, producing biaryl products with various substituents in high yields up to 97\%. Dual-activation of K+ and t-BuO-, and π,π-stacking interaction between the substrate and the polymer backbone may account for the superior activity.",

author = "Zhenghui Liu and Zhenzhen Yang and Leiduan Hao and Xinwei Liu and Hongye Zhang and Bo Yu and Zhimin Liu",

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T2 - highly efficient catalysts for C-H arylation of benzene

AU - Liu, Zhenghui

AU - Yang, Zhenzhen

AU - Hao, Leiduan

AU - Liu, Xinwei

AU - Zhang, Hongye

AU - Yu, Bo

AU - Liu, Zhimin

PY - 2016

Y1 - 2016

N2 - Polyureas derived from CO2 and diamines were effective for C-H arylation of benzene in the presence of t-BuOK, producing biaryl products with various substituents in high yields up to 97%. Dual-activation of K+ and t-BuO-, and π,π-stacking interaction between the substrate and the polymer backbone may account for the superior activity.

AB - Polyureas derived from CO2 and diamines were effective for C-H arylation of benzene in the presence of t-BuOK, producing biaryl products with various substituents in high yields up to 97%. Dual-activation of K+ and t-BuO-, and π,π-stacking interaction between the substrate and the polymer backbone may account for the superior activity.

UR - https://www.scopus.com/pages/publications/85007205633

U2 - 10.1039/c6nj02785g

DO - 10.1039/c6nj02785g

M3 - Article

AN - SCOPUS:85007205633

SN - 1144-0546

VL - 41

SP - 51

EP - 55

JO - New Journal of Chemistry

JF - New Journal of Chemistry

IS - 1

ER -

Polyureas derived from CO₂ and diamines: highly efficient catalysts for C-H arylation of benzene

Abstract

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