Poly(ethylene-covinyl alcohol) functionalized single-walled carbon nanotubes and related nanocomposites

K. A.Shiral Fernando, Yi Lin, Bing Zhou, Michael Grah, Ronalda Joseph, Lawrence F. Allard, Ya Ping Sun

Research output: Contribution to journalArticlepeer-review

33 Scopus citations

Abstract

Single-walled carbon nanotubes (SWNTs) were functionalized by poly(ethylene-co-vinyl alcohol) (EVOH) copolymer under carbodiimide-activated esterification reaction conditions. Similar to the parent EVOH copolymer, the EVOH-functionalized carbon nanotubes are soluble in highly polar solvent systems such as DMSO and hot ethanol-water mixtures. The soluble EVOH-SWNT sample was characterized by various techniques, including optical absorption, Raman, NMR, electron microscopy, and thermogravimetric analysis. The common solubility of EVOH and EVOH-SWNT allowed their intimate mixing in solution, and thus the fabrication of nanocomposites in which the SWNTs are homogeneously dispersed in the polymer matrix.

Original languageEnglish
Pages (from-to)1050-1054
Number of pages5
JournalJournal of Nanoscience and Nanotechnology
Volume5
Issue number7
DOIs
StatePublished - 2005
Externally publishedYes

Keywords

  • Carbon Nanotubes
  • Functionalization
  • Nanocomposites
  • Poly(ethylene-co-vinyl alco-hol)
  • Solubility

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